Godovikovite

godovikovite

coal seam fires

tschermigite

Images

Formula: (NH4)Al(SO4)2
Anhydrous sulphate
Crystal System: Trigonal
Specific gravity: 2.53 measured, 2.52 calculated
Hardness: 2
Streak: White
Colour: White, colourless in thin section
Solubility: Slowly soluble in water
Environments

Fumeroles
Coal-seam fires

Godovikovite occurs as reaction crusts around outlets releasing sulphuric acid from burning coal heaps; it is associated with unspecified anhydrous calcium and magnesium sulphates (HOM).
Godovikovite hydrates to tschermigite at room temperature, and it may occur in burning coal dumps as a dehydration product of tschermigite (Mindat).

Localities

At the type locality, Kopeysk, Chelyabinsk Oblast, Russia, godovikovite forms white, compact or porous chalky aggregates of fine hairs, 0.001 to 0.015 mm in size, in the burning dumps of coal mines. It is one of the main constituents of the sulphate crusts formed by reaction of sulphuric acid with the material in the dumps. Together with (Al,Fe)2(SO4)3, it occurs in the lower, hotter zones, which are up to 5 cm thick and up to 1 m2 in area (AM 75.241-242).
Spontaneous fires occur on many coal dumps and are known to rage for years or decades, forming many rare high-temperature minerals (Mindat).

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