Auropolybasite

auropolybasite

auropearceite

selenostephanite

rozhdestvenskayaite-(Zn)

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Formula: [Ag9AuS4][Ag6Sb2S7]
Valence: [Ag1+9Au1+S2-4][Ag1+6Sb3+2S2-7]
Sulphantimonite, pearceite-polybasite group, silver-, gold- and antimony- bearing mineral
Crystal System: Trigonal
Specific gravity: 6.622 calculated
Hardness: About 3
Streak: Black
Colour: Dark grey to black
Environments

Hydrothermal environments

Auropolybasite is a new mineral, approved in 2024 and to date (January 2026) it has been reported only from the type locality. It is the first member of the pearceite-polybasite group with essential Au. (AM 109.2173-2174)

Localities

At the type locality, Šibeničný vrch, Nová Baňa, Žarnovica District, Banská Bystrica Region, Slovakia, auropolybasite and auropearceite were found as anhedral grains up to 0.2 mm in size, usually rimmed by acanthite. Other associated minerals include argentopolybasite, argentopearceite, pyrargyrite, proustite, stephanite, selenostephanite, rozhdestvenskayaite-(Zn), zvěstovite-(Zn), zvěstovite (Fe), naumannite, Au-Ag alloys, uytenbogaardtite, iodargyrite and bromargyrite. They are dark grey to black, opaque, with a black streak and metallic lustre. They are brittle with no observable cleavage and with a conchoidal fracture.
auropolybasite and auropearceite form in the waning stages of epithermal systems, from reduced, S-rich and low-salinity fluids that transport Au, Ag, Sb and As in the form of thiocomplexes ("thio" is a prefix used in chemistry to indicate the presence of sulphur in a compound). These fluids are unable to transport Cu, Pb or Zn, thus explaining the chemical composition of these minerals and the entire mineral assemblage (AM doi:10.2138/am-2025-9806).

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