Spertiniite

spertiniite

diopside

grossular

vesuvianite

Images

Formula: Cu(OH)2
Hydroxide
Crystal System: Orthorhombic
Specific gravity: 3.93 measured, 3.94 calculated
Colour: Light blue, blue-green
Solubility: Synthetic material is soluble in cold water, decomposes in hot water and is soluble in acids
Environments

Hydrothermal environments

Localities

The type locality is the Jeffrey mine, Val-des-Sources, Les Sources RCM, Estrie, Quebec, Canada. Spertiniite is a very rare mineral, found in a rodingite dyke exposed in the open pit near the contact with the host serpentinised dunite. This portion of the rodingite consists primarily of fine grained, dense, white diopside and grossular, partly coated with pale green vesuvianite. Chalcocite commonly constitutes the core of the botryoidal masses of spertiniite, which also contain atacamite. Minor amounts of copper are associated with spertiniite in the rodingite. It appears that the spertiniite is a product of the supergene alteration of chalcocite. In the area where the spertiniite was found, percolating water was found to be oxidising, and also quite alkaline, with pH=9.2. These unusual conditions preclude the formation of copper sulphates, which are the normal alteration products of chalcocite. Here the solubility is due almost entirely to the cupric ion, Cu2+, and the stable solid phase is cupric hydroxide Cu2+(OH)2. Any chloride ions available in the groundwater have been essential to the formation of atacamite (CM 19.337-340).

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