Szilagyiite

szilagyiite

Images

Formula: NaCa3(UO2)(CO3)3(SeO3)F(H2O)6
Valence: NaCa3(U6+O2)(CO3)3(Se4+O3)F(H2O)6
Uranyl carbonate-selenite
Crystal system: Trigonal
Specific gravity: 3.16 measured, 3.17 calculated
Hardness: 2 to 3
Streak: Pale yellow-green
Colour: Yellow-green
Luminescence: Fluoresces dimly green under long wave UV and 405 nm illumination but does not fluoresce under short wave UV
Environments

Sedimentary environments
Hydrothermal environments

Szilagyiite is a new mineral, approved in 2024 and to date (May 2026) reported only from the type locality

Localities

The type locality, the Pickett Corral Mine, Montrose County, Colorado, USA, is an inactive uranium and vanadium mine in the Uravan mineral belt of the Colorado Plateau. The mine is notable as the type locality for several rare vanadate minerals including pseudodickthomssenite, bicapite and trebiskyite. These vanadates each occurred in distinct assemblages from that bearing szilagyiite, which is the first uranium-bearing type species for the locality. In the sandstone-hosted mine, uranium is primarily present as uraninite or coffinite, while vanadium occurs predominantly as montroseite and corvusite, or in sheet silicates such as vanadian clays or roscoelite.
The original uranium and vanadium ores were deposited when metal-laden groundwater encountered reducing conditions in the presence of abundant organic matter (asphaltite). In most cases, the strongest secondary mineralisation occurs intimately within asphaltite layers and pods. Post-mining oxidation has produced highly diverse secondary mineralisation throughout the Picket Corral mine due to ongoing dissolution and recrystallisation. High CO2 content, resulting from decomposition of calcite by acidic waters derived from decaying sulphides, coupled with periods of high humidity were likely necessary for the formation of szilagyiite. The szilagyiite occurs in association with andersonite, schröckingerite, crusts of magselite and a potentially new Na–Ca-uranyl carbonate-selenite-sulfate with a complex structure related to szilagyiite and schröckingerite. Material containing szilagyiite was extracted from a small (~0.25 m) asphaltite-laden sandstone lens richly coated by andersonite with sparse but dense patches of fine-grained ferroselite. The source of Se in szilagyiite is clearly oxidised ferroselite, given its close association within several centimeters.
Szilagyiite occurs as dense yellow-green rosettes up to 1 mm wide and subparallel tablets up to ~200 µm in size, with frequent twinning by inversion and one perfect cleavage. It has a pale yellow-green streak and the crystals are transparent with vitreous lustre and a brittle, uneven fracture (Journal of Geosciences 70.3.177-188).
Szilagyiite from the Pickett Corral Mine - Image

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