Burroite

burroite

montroseite

corvusite

schindlerite

Images

Formula: Ca2 (NH4)2 (V10O28).15H2 O
Decavanadate
Crystal System: Triclinic
Specific gravity: 2.43 measured
Hardness: 1½ to 2
Streak: Yellow
Colour: Orange-yellow
Luminescence: Not fluorescent under UV
Solubility: At room temperature, burroite is very slowly soluble in water and rapidly soluble in dilute hydrochloric acid
Environments

Sedimentary environments
Hydrothermal environments

Burroite is relatively new mineral, approved in 2016 and to date (October 2022) reported only from the type locality.

Localities

At the type locality, the Burro Mine, Slick Rock Mining District, San Miguel County, Colorado, USA, U6+ and V4+ were transported as dissolved species in weakly alkaline, moderately reducing CO2--rich groundwater, and, upon encountering more reducing conditions by contacting carbonaceous material and H2S, were deposited as uraninite and montroseite. Subsequent exposure of those minerals to near-surface solutions, which had reacted with sulphide minerals and become more acidic, resulted in the crystallisation of numerous secondary phases, including burroite.
Burroite is very rare; it occurs as orange-yellow, somewhat flattened prisms up to 2 mm in length on montroseite- and corvusite- bearing sandstone in an apparently NH4-rich secondary assemblage that also contains the NH4-bearing decavanadates schindlerite and wernerbaurite. Other secondary minerals found in the mine include barnesite, gypsum, hewettite, magnesiopascoite, metamunirite, metarossite, navajoite, pascoite, rossite and sherwoodite.
Burroite forms from the oxidation of montroseite-corvusite assemblages in a moist environment. The NH4 presumably derives from organic matter in the deposit (CM 55.473-481).

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