Jamborite

jamborite

millerite

gaspeite

mcguinnessite

Images

Formula: Ni2+1-xCo3+x(OH)2-x(SO4)x.nH2O [x ≤ ⅓; n ≤ (1-x)]
Hydroxide, nickel- and cobalt- bearing mineral
Crystal System: Trigonal
Specific gravity: 2.67 measured, 2.69 calculated
Colour: Green
Solubility: Insoluble in water but slowly soluble in cold dilute hydrochloric acid without any visible reaction
Environments

Hydrothermal environments

Jamborite was redefined in 2014.

Localities

There are four co-type localities, Ca' dei Ladri, Gaggio Montano, Metropolitan City of Bologna; Monteacuto Ragazza, Grizzana Morandi, Metropolitan City of Bologna; Sasso delle Lucine, Castelluccio di Moscheda, Montese, Modena Province; Rio Vesale, Vesale, Sestola, Modena Province; all at Emilia-Romagna, Italy.

At the type localities jamborite was found associated with millerite in small cavities in ophiolitic rocks. It occurs as a green coating on the walls of cavities lined by calcite, dolomite and quartz crystals. The coatings seem to consist of sheaves of transparent, single crystals pseudomorphous after millerite. The interior zones of some "crystals" contain unaltered millerite. All gradations occur between pure millerite and jamborite.
Jamborite is included within quartz and calcite in some places. Each aggregate of jamborite consists of microcrystalline individuals, either acicular or lamellar, and of crypto-crystalline or even isotropic patches that chiefly occur in the centre of an aggregate. These facts, together with the occurrence of pseudomorphs of jamborite after millerite, indicate that jamborite did not form by simple weathering of millerite but by gradual, probably low-temperature, hydrothermal alteration.
Millerite was formed in an early hydrothermal stage under reducing conditions. Later, more oxidising alteration converted millerite into nickel hydroxide. The millerite underwent hydrolysis and then partial oxidation. The hydrolysis led to a partial replacement of S by OH, yielding an isotropic material whose remnants still can be seen within the crystalline jamborite. The more crystalline jamborite could have been produced by a slow oxidation inward from the surface, gradually producing an ordered crystalline structure (AM 58.835-839).

At the Nakauri mine, Shinshiro city, Aichi Prefecture, Japan, jamborite occurs in serpentinites, associated with gaspéite, glaukosphaerite and mcguinnessite (HOM).

At Halls Gap, Lincoln county, Kentucky, USA, another occurrence of what may be jamborite has been found. The pale green mineral occurs as an alteration product of capillary millerite in quartz-lined geodes (AM 58.835-839).

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