Kenorozhdestvenskayaite-(Fe)

kenorozhdestvenskayaite-(Fe)

pyrargyrite

pyrrhotite

siderite

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Formula: [Ag6]4+(Ag4Fe2+2)Sb4S12
Sulphantimonite, rozhdestvenskayaite subgroup, tetrahedrite group
Crystal System: Isometric
Specific gravity: 5.329 calculated
Colour: Black
Environments

Hydrothermal environments

Kenorozhdestvenskayaite-(Fe) is a new mineral, approved in 2022 and to date (September 2024) reported only from the type locality

Localities

At the type locality, the Yindongpo Mine, Weishancheng ore field, Tongbai County, Nanyang, Henan, China, kenorozhdestvenskayaite-(Fe) is a tetrahedrite group mineral containing a natural [Ag6]4+ cluster. It occurs at the edges of galena crystals as anhedral grains of 2 to 20 μm in size and is associated with pyrargyrite, pyrrhotite and siderite in the hydrothermal gold deposit. The presence of the unusual mineral assemblages, ie pyrrhotite and pyrargyrite, as well as the other keno-end-member tetrahedrites, indicates a low sulphidation state for the mineralisation stage, probably a result of the fluid boiling process in an open system that likely contributed to the formation of S-deficient tetrahedrites.
[Ag6]4+ clusters are extremely rare in nature (only found in silver-rich tetrahedrite group minerals), but the kinds of natural conditions that promote the formation of subvalent hexasilver clusters in tetrahedrite group minerals are still unclear (AM 109.7.1275-1283).

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