Formula: Fe(CO3) carbonate
Specific gravity: 3.7 to 3.9
Hardness: 4 to 4½
Colour: Yellowish white, yellowish brown to dark brown
Solubility: Moderately soluble in hydrochloric, sulphuric and nitric acid
Common impurities: Mn,Mg,Ca,Zn,Co
Siderite is frequently found mixed with clay minerals, in concretions with
concentric layers. As black-band ore it is found, contaminated by carbonaceous material, in extensive stratified
formations in shale and commonly associated with coal measures. It is also formed
by the action of iron-rich solutions on limestone. Siderite is a common
vein mineral associated
with silver minerals, pyrite,
galena in the oxidation zone of
hypothermal (high temperature) hydrothermal veins.
Siderite may be found in limestone, and in the alkaline syenite pegmatites of Mont Saint-Hilaire, Canada (R&M 93.2.147).
At Mount Moliagul, Moliagul, Central Goldfields Shire, Victoria, Australia, aggregates to 3 cm of siderite crystals are found with calcite in cavities in quartz (AJM 21.1.44).
At Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Quebec, Canada, siderite pseudomorphs after serandite have been found (KL p159).
At the Panasquiera mine, Portugal, siderite pseudomorphs after apatite have been found (KL p157).
At the Turt mine, Muramures, Romania, siderite pseudomorphs after calcite have been found (KL p158).
At the Aggenys mine, South Africa, siderite pseudomorphs after sphalerite have been found (KL p160).
At Teller county, Colorado, USA, a goethite pseudomorph after siderite has been found with microcline (KL p145).
At the Kabwe mine, Central Province, Zambia, siderite has been found associated with smithsonite (R&M 94.2.134).
chalcopyrite, arsenopyrite, CO2 and O2 to Fe-tennantite, siderite and sulphur
10CuFeS2 + 4FeAsS + 4CO2 + 8O2 → Cu10Fe2As4S13 + 4Fe(CO3) + 11/2S2
olivine and CO2 to enstatite- ferrosilite and magnesite-siderite
(Mg,Fe)2SiO4 + CO2 → (Mg,Fe2+)SiO3 + (Mg,Fe)CO3
(DHZ 2A p139)
siderite, oxygen and H2O to hematite and silicic acid
2Fe2CO3 + O2 + 4H2O → 2Fe2O3 + 2H2CO3
On prolonged exposure to the air Fe2+ compounds are oxidised to Fe3+ compounds according to reactions such as the one above (KB p334).
siderite and quartz to fayalite and CO2
2Fe(CO3) + SiO2 = Fe2+2(SiO4) + 2CO2
(DHZ 1A p265)
Mg-rich siderite and quartz to olivine, orthopyroxene and CO2
3(Fe,Mg)(CO3)→ (Fe,Mg)2SiO4 + 2SiO2 → (Fe,Mg)2SiO4 + 3CO2
(DHZ 1A p266) Fe-tetrahedrite, siderite and sulphur to chalcopyrite, stibnite, CO2 and O2
Cu10Fe2Sb4S13 + 8Fe(CO3) + 13/2S2 → 10CuFeS2 + 2Sb2S3 + 8CO2 + 4O2
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