Native element, sulphur group, paramorph of clinosulphur and rosickýite
Crystal System: Orthorhombic
Specific gravity: 2.07 measured, 2.076 calculated
Colour: Yellow, brownish yellow, greenish yellow
With a low melting point of 113 degrees C, sulphur burns readily in air, with a low blue flame, and gives off choking fumes of sulphur-dioxide - acrid odour (forms sulphurous and eventually sulphuric acid in air).
Solubility: Insoluble in water, hydrochloric, nitric and sulphuric acid
Common impurities: Se,Te
Volcanic sublimates (common)
Most native sulphur is formed by reduction of sulphates, especially in salt domes, where it forms by
decomposition of calcium sulphate. It also often occurs at or near the crater rims of active or extinct volcanoes,
derived from volcanic gases and
associated with realgar and
cinnabar. The volcanic gases may produce sulphur as a direct sublimation product
or by the incomplete oxidation of
hydrogen sulphide gas. In sedimentary rocks sulphur is most commonly associated with
gypsum and limestone.
The Two Mile and Three Mile deposits, Paddy's River, Paddys River District, Australian Capital Territory, Australia, are skarn deposits at the contact between granodiorite and volcanic rocks. sulphur is a secondary native element that occurs as crystals up to 1 mm in limonite from the dump, and also associated with copiapite. It can be seen forming as a breakdown product of melanterite associated with oxidising pyrite (AJM 22.1.38).
At the Malo-Bystrinskoe lazurite deposit, Malaya Bystraya River Valley, Slyudyanka, Lake Baikal area, Irkutsk Oblast, Russia, sulphur is found with lazurite in calcite (FM 75879).
At the Ball Eye mine and quarry, Cromford, Derbyshire, England, UK, native sulphur has been reported with anglesite in oxidised galena (RES p74).
At Tsumeb, Namibia, sulphur has been found with schultenite, anglesite and galena (R&M 93.6.548).
At Cookes Peak mining district, Luna county, New Mexico, USA, sulphur is found in small cavities in oxidising galena (R&M 94.3.236).
chalcopyrite, arsenopyrite, CO2 and O2 to Fe-tennantite, siderite and sulphur
10CuFeS2 + 4FeAsS + 4CO2 + 8O2 → Cu10Fe2As4S13 + 4Fe(CO3) + 11/2S2
chalcopyrite, arsenopyrite and sulphur to Fe-tennantite and pyrite
10CuFeS2 + 4FeAsS + 13/2S2 → Cu10Fe2As4S13 + 12FeS2
This reaction occurs at a comparatively low temperature (CM 28.725-738).
chalcopyrite, arsenopyrite and sulphur to Fe-tennantite and troilite
l0CuFeS2 + 4FeAsS + l/2S2 → Cu10Fe2As4S13 + l2FeS
chalcopyrite, stibnite and sulphur to Fe-tetrahedrite and pyrite
10 CuFeS2 + 2 Sb2S3 + 3/2 S2 → Cu10Fe2As4S13 + 8FeS2
covellite and ferric sulphate to ferrous sulphate, copper sulphate and sulphur
CuS + Fe2(SO4)3 → 2FeSO4 + CuSO4 + S
Covellite may be oxidised by the strong oxidising agent ferric sulphate according to the above reaction to form sulphur (AMU/b3-3-7.htm).
enargite and pyrite to Fe-tennantite, chalcopyrite and sulphur
4Cu3AsS4 + 4FeS2 → Cu10Fe2As4S13 + 2CuFeS2 + 7/2S2
skinnerite to chalcocite, antimony and sulphur
2Cu3SbS3 → 3Cu2S + 2Sb + 3/2S2
stibnite and pyrite to berthierite and sulphur
Sb2S3 + FeS2 → FeSb2S4 + l/2S2
Fe-tetrahedrite, berthierite and sulphur to chalcopyrite and stibnite
Cu10Fe2Sb4S13 + 2FeSb2S4 + 11/2S2 → 10CuFeS2 + 4Sb2S3
Fe-tetrahedrite, siderite and sulphur to chalcopyrite, stibnite, CO2 and O2
Cu10Fe2Sb4S13 + 8Fe(CO3) + 13/2S2 → 10CuFeS2 + 2Sb2S3 + 8CO2 + 4O2
Zn-tetrahedrite to chalcocite, antimony, sphalerite and sulphur
Cu10Zn2Sb4S13 → 5Cu2S + 4Sb + 2ZnS + 3S2
Zn-tetrahedrite to skinnerite, antimony, sphalerite and sulphur
3Cu10Zn2Sb4S13 → 10Cu3SbS3 + 2Sb + 6ZnS + 3/2S2
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