Formula: CaMg(SiO4) nesosilicate (insular SiO4 groups)
Specific gravity: 3.2
Colour: Colourless, grey or greenish
Solubility: Insoluble in water, nitric and sulphuric acid; soluble with gelatinous residue in hydrochloric acid
Volcanic igneous environments
Monticellite occurs as a relatively common mineral formed during metamorphism of siliceous
dolostones, in contact
metamorphic deposits between limestones
and olivine gabbros and in
skarns at granite-dolomitic limestone contacts. It occurs less frequently in
It is a mineral of the granulite facies.
During the progressive metamorphism of silica-rich dolostones the following approximate sequence of mineral formation is often found, beginning with the lowest temperature product: talc, tremolite, diopside, forsterite, wollastonite, periclase, monticellite
åkermanite to monticellite and wollastonite
Ca2MgSi2O7 → CaMg(SiO4) + CaSiO3
diopside, forsterite and calcite to monticellite and CO2
CaMgSi2O6 + Mg2SiO4 + 2CaCO3 → 3CaMgSiO4 + 2CO2
This reaction requires a high temperature (DHZ 2A p271).
forsterite and åkermanite to diopside and monticellite
Mg2SiO4 + 2Ca2MgSi2O7 → CaMgSi2O6 + 3CaMg(SiO4)
forsterite, calcite and quartz to monticellite and CO2
Mg2SiO4 + 2 CaCO3 + SiO2 → 2CaMg(SiO4) + 2 CO2
forsterite, diopside and calcite to monticellite and CO2
Mg2SiO4 + CaMgSi2O6 + 2 CaCO3 ⇌ 3CaMg(SiO4) + 2 CO2
This reaction occurs during contact metamorphism of magnesian limestone (DHZ 1A p353).
grossular, diopside, monticellite, calcite and H2O to vesuvianite, quartz and CO2
10Ca3Al2(SiO4)3 + 3CaMgSi2O6 + 3CaMg(SiO4) + 2CaCO3 + 8H2O ⇌ 2Ca19Al10Mg3(SiO4)10 (Si2O2)4O2(OH)8 + 3SiO2 + 2CO2
A common association in calc-silicate metamorphism can be represented by the above equation. Vesuvianite stability will tend to increase with increasing water and decrease as the activity of CO2 rises. (DHZ 1A p714).
monticellite and CO2 to åkermanite, forsterite and calcite
3CaMgSiO4 + CO2 ⇌ Ca2MgSi27 + Mg2O7 + CaCO3
At 4.3 kbar pressure the equilibrium temperature is about 890oC (granulite facies) (DHZ 1A p357).
monticellite and diopside to åkermanite and forsterite
3CaMgSiO4 + CaMgSi2O6 ⇌ 2Ca2MgSi2O7 + Mg2O7
At a pressure of 4.3 kbar the equilibrium temperature is about 890oC (granulite facies) (DHZ 1A p357).
monticellite and spurrite to merwinite and calcite
2CaMg(SiO4) + Ca5(SiO4)2(CO3) ⇌ 2Ca3Mg(SiO4)2 + CaCO3
monticellite, spurrite and quartz to merwinite and CO2
5CaMg(SiO4) + Ca5(SiO4)2(CO3) + SiO2 ⇌ 5Ca3Mg(SiO4)2 + 2CO2
Common impurities: Ti,Al,Fe,Mn,Zn,H2O
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