Stoiberite

stoiberite

shcherbinaite

bannermanite

mcbirneyite

Images

Formula: Cu5O2(VO4)2
Anhydrous vanadate
Crystal System: Monoclinic
Specific gravity: 5.0 measured, 4.96 calculated
Streak: Reddish brown
Colour: Black
Luminescence: Not fluorescent under UV
Solubility: Soluble in dilute sulphuric acid
Environments

Fumeroles

Localities

The type locality, the Izalco Volcano, Sonsonate Department, El Salvador, is a basaltic and andesitic stratovolcano that has been intermittently active since its birth in 1770. In 1963, shcherbinaite, the first-known high-temperature vanadium mineral, was discovered in the summit crater fumaroles. Since that time, five other high-temperature vanadium sublimates have been isolated from the fumarolic mineral suite. These are bannermanite and four copper vanadates, stoiberite, mcbirneyite, ziesite and fingerite. These minerals formed as sublimates from vanadium-bearing gases at temperatures up to 760oC.
Stoiberite is found in one of five major fumaroles in the summit crater. ln 1964, when the mineral was first discovered, the temperature of the fumarole was 450oC. The temperature of the fumarole in Novembet, 1978, had fallen to 89oC, and only small amounts of stoiberite were found. It occurs as a black incrustation in the oxide zone of the fumarole. The crystals are less than 100 microns in size and coat basaltic breccia fragments (AM 64.941-944).
Stoiberite from the Izalco Volcano - Image

At the Lichtenberg Absetzer dump, Kauern, Greiz District, Thuringia, Germany, stoiberite has been found (Mindat photo).
Stoiberite from the Lichtenberg Absetzer dump - Image

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