Chladniite

chladniite

kamacite

schreibersite

merrillite

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Formula: Na3CaMg11(PO4)9
Anhydrous phosphate, fillowite group

Stornesite-(Y) is an yttrium-bearing variety of chladniite

Crystal System: Trigonal
Specific gravity: 3.017 calculated
Hardness: 4½ to 5
Streak: White
Colour: Colourless
Common impurities: Fe,Mn,Si
Environments

Pegmatites ?
Meteorites

Localities

At the Graves Nunataks 12510 meteorite, Graves Nunataks meteorites, Wisconsin Range, Eastern Antarctica, Antarctica, the first widespread occurrence of rare chladniite was observed in the primitive achondrite. Numerous 1 to 500 µm chladniite grains were found, often on the margins between silicate clasts and the kamacite portions of the large metal veins that permeated through the sample. The largest chladniite grains are associated with merrillite, kamacite, taenite, troilite, albite, forsterite, diopside and enstatite, with a few tiny chladniite grains and an apatite grain enclosed within merrillite.
Meteoritic chladniite likely formed through oxidation of schreibersite, scavenging Na from albite, Ca from diopside, Mg from enstatite/forsterite, Fe from kamacite/taenite, and Mn from alabandite/chromite when available (AM 109.1513–1522).

The Graves Nunataks 95209 meteorite, Graves Nunataks meteorites, Wisconsin Range, Eastern Antarctica, Antarctica, is a primitive achondrite. Numerous grains of an orthophosphate intermediate in composition between farringtonite and graftonite/sarcopside are found in association with iron- and manganese- rich chladniite. The chladniite probably formed both through replacement of magnesium-rich graftonite and directly by reaction of metal with silicates, including plagioclase. Apatite appears to have played only a minor role in the formation of these phosphates (AM 84.1354-1359).

At the Tablada I pegmatite, Parroquia District, Pocho Department, Córdoba Province, Argentina, chladniite, previously found only in meteorites, was identified in the pegmatite as inclusions in beusite.
The refined crystal structure of pegmatitic chladniite differs from the meteoritic one in the cation ordering (Mg, Fe + Mn and Ca) at the various metal sites, with Mn being dominant at the M(1) position (EJM 29.2.287–293). Hence it may be that this is not a true chladniite.

At the type locality, the Carlton meteorite, Carlton, Hamilton County, Texas, USA, a single grain of chladniite was identified in a polished section of the iron meteorite. The chladniite occurs within and near the edge of a silicate-bearing inclusion that is approximately 5 x 5 mm2 in size. Chlorapatite is the dominant mineral in the inclusion; olivine, pyroxene and plagioclase occur as mono or polymineralic clusters within chlorapatite and along the outer portions of the inclusion. Schreibersite occurs as millimeter-sized grains, and an intergrowth of micron-sized Fe, Ni and FeS occurs as millimeter-sized pockets at the edges of the inclusion; the entire inclusion is rimmed by kamacite.
Chladniite occurs as a single grain, which measures 175 x 975 µ2. Irregular fractures are filled with hydrated iron oxides of terrestrial origin (AM 79.375-380).

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