Dinilawiite

dinilawiite

hydroredmondite

steverustite

sulfatoredmondite

Images

Formula: [Pb4O2Al(OH)5]2(S2O3)2.H2S2Osub>3)(H2O)5
Thiosulphate (containing the group (S2O3)2-)
Crystal System: Monoclinic
Specific gravity: 4.727 calculated for the empirical formula, and 4.741 calculated for the ideal formula
Hardness: 2
Streak: White
Colour: Colourless
Luminescence: Does not fluoresce under long wave or short wave UV
Solubility: In room-temperature dilute hydrochloric acid, slowly becomes cloudy and then very slowly dissolves
Environments

Hydrothermal environments

Dinilawiite is a new mineral, approved in 2023 and to date (January 2025) reported only from the type locality.

Localities

The type locality, the Redmond Mine, Waterville Lake, Haywood County, North Carolina, USA, is a very small and long-inactive lead - zinc mine. The highly unusual secondary assemblage lead - zinc - copper sulphates, thiosulphates and carbonates found here is particularly noteworthy for yielding phases with structures containing rare, and in some cases novel, structural units based on short Pb2+–O bonds.
The name "dinilawiite" is based on the Cherokee word meaning twin, because the mineral is ubiquitously twinned. The ore, consisting mainly of galena and sphalerite with lesser chalcopyrite, occurs in an epithermal vein system consisting of disconnected sulphide-bearing quartz lenses near the contact between a granite gneiss and a mica schist. The new minerals occur in a localised unusual secondary mineral assemblage.
Dinilawiite occurs in vugs in massive galena - sphalerite - chalcopyrite - quartz in close association with hydroredmondite, steverustite, sulfatoredmondite and susannite.
Dinilawiite crystals occur as flattened tablets with angled striations, up to about 0.4 mm across. The mineral is colourless but sometimes appears light reddish brown due to inclusions or the transmitted colour of the matrix. The streak is white and the lustre is vitreous (CJMP 62.871-879).
Dinilawiite from the Redmond Mine - Image

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