Hureaulite

hureaulite

lithiophilite

heterosite

triphylite

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Formula: Mn2+5(PO3OH)2(PO4)2.4H2O
Hydrated acid phosphate, hureaulite group, manganese-bearing mineral
Crystal System: Monoclinic
Specific gravity: 3.15 to 3.20 measured, 3.23 calculated
Hardness: 5
Streak: Nearly white
Colour: Commonly pink to colourless, also red, orange, orange-red, reddish brown, yellowish brown, violet-rose, amber, grey
Solubility: Readily soluble in acids
Environments

Pegmatites

Hureaulite is a late-stage secondary mineral formed by alteration of primary phosphates in complex granite pegmatites, associated with lithiophilite, triphylite, heterosite, rockbridgeite, cacoxenite, vivianite, fairfieldite, dickinsonite, eosphorite, stewartite, strengite, phosphosiderite, roscherite, hydroxylapatite, jahnsite and triplite (HOM, Mindat).
Hureaulite is one of the more persistent low temperature transition metal phosphate hydrates derived from hydrothermal attack of triphylite-lithiophilite crystals in granite pegmatites. Hureaulite characteristically occurs very late in the secondary phosphate paragenetic sequence (AM 58.302-307).

Localities

At the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Nouvelle-Aquitaine, France, hureaulite occurs in a zone of altered triphylite in a granite pegmatite, associated with rockbridgeite, cacoxenite, and vivianite in cavities in heterosite (Dana, Mindat).

At the Stewart pegmatite, Pala, San Diego county, California, USA, hureaulite occurs with sicklerite, phosphosiderite and stewartite in altered lithiophilite (Dana, AM 70.395-408).

At Branchville, Ridgefield, Fairfield county, and the Strickland Quarry, Portland, Middlesex county, Connecticut, USA, hureaulite is a secondary mineral found with fairfieldite, dickinsonite, reddingite, and eosphorite as hydrothermal alteration of lithiophilite (Dana).

At the Emmons pegmatite, Greenwood, Oxford county, Maine, USA, hureaulite is a common replacement of rhodochrosite that is associated with lithiophilite. Stewartite and phosphoferrite are common associated minerals. The Emmons pegmatite is an example of a highly evolved boron-lithium-cesium-tantalum enriched pegmatite (R&M 94.6.508-509).

At the Palermo number 1 and Fletcher mines, Groton, Grafton county, New Hampshire, USA, hureaulite occurs in weathered triphylite with phosphosiderite, strengite and heterosite (Dana).

At the Keyes Mica Quarries, Orange, Grafton County, New Hampshire, USA, the pegmatites are beryl-type rare-element (RE) pegmatites.
The Number 1 mine exposed a pegmatite that shows the most complex zonation and diverse mineralogy of any of the Keyes pegmatites. Six zones are distinguished, as follows, proceeding inward from the margins of the pegmatite:
(1) quartz-muscovite-plagioclase border zone, 2.5 to 30.5 cm thick
(2) plagioclase-quartz-muscovite wall zone, 0.3 to 2.4 metres thick
(3) plagioclase-quartz-perthite-biotite outer intermediate zone, 0.3 to 5.2 metres thick, with lesser muscovite
(4) quartz-plagioclase-muscovite middle intermediate zone, 15.2 to 61.0 cm thick
(5) perthite-quartz inner intermediate zone, 0.9 to 4.6 meters thick
(6) quartz core, 1.5 to 3.0 metres across
The inner and outer intermediate zones contained perthite crystals up to 1.2 meters in size that were altered to vuggy albite-muscovite with fluorapatite crystals. This unit presumably was the source of the albite, muscovite, fluorapatite, quartz and other crystallised minerals found in pieces of vuggy albite rock on the dumps next to the mine.
The middle intermediate zone produced sheet mica with accessory minerals including tourmaline, graftonite, triphylite, vivianite, pyrite, pyrrhotite, and beryl crystals to 30.5 cm long and 12.7 cm across.
Hureaulite was discovered at the Keyes No. 1 mine as unusual orange masses to cabinet size and lustrous pink to orange crystals to about 3 mm. Associated minerals include albite, muscovite, triphylite, rockbridgeite, lazulite-scorzalite, pink phosphosiderite crystals and pyrite (R&M 97.4.318).

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