Mannardite

mannardite

norsethite

sulvanite

barytocalcite

Images

Formula: Ba(Ti6V3+2)O16
Oxide, priderite group, hollandite supergroup, barium-, titanium- and vanadium- bearing mineral
Crystal System: Tetragonal
Specific gravity: 4.12 measured, 4.28 calculated
Hardness: 7
Streak: White to greyish white
Colour: Jet-black
Environments

Sedimentary environments
Hydrothermal environments

Localities

There are two co-type localities,
the Rough claims, Kechika River, Sifton Pass, Liard Mining Division, British Columbia, Canada
and
the Shiti Mine, Hanbin District, Ankang, Shaanxi, China.

At the Gacun Mine, Maqiong, Baiyü County, Garzê Autonomous Prefecture, Sichuan, China, mannardite occurs in a silver-bearing polymetallic deposit (HOM).

At the Rough claims, Kechika River, Sifton Pass, Liard Mining Division, British Columbia, Canada, mannardite occurs in narrow quartz-carbonate veins that cut a Devonian (419.2 to 358.9 million years ago) shale and siltstone sequence. The veins containing mannardite are apparently nearly vertical and appear to post-date the folding of the sedimentary strata.
Three distinct types of mannardite-bearing vein material have been collected to date.
Type A material, which contains the largest crystals of mannardite, is unweathered, massive to somewhat vuggy, milky vein quartz in which cavities have been completely infilled with crystalline patches up to 1 cm in diameter of cream-coloured barytocalcite and elongate flattened crystals of greenish grey norsethite. The carbonates postdate the mannardite. A generation of small euhedral clear crystals of quartz lines the vugs, and mannardite, as euhedral terminated crystals, is found growing within and upon these.
Type-B material is the weathered equivalent of type A, in which almost all the barytocalcite has been altered to form pockets of very fine-grained powdery white baryte. Norsethite is very rare, and the quartz also contains a few crystals of sulvanite as bronzy black, tarnished cubes to 5 mm in size. In type-B material, the mannardite usually forms radial clumps of terminated crystals in the quartz; most crystals are about 0.2 x 0.2 x 1 mm3. In general, mannardite appears to be contemporaneous with the sulvanite but earlier than the carbonates and most of the quartz.
Type-C material consists of late-stage fracture fillings of columnar quartz centrally cross-cutting type-B veins. Mannardite occurs as elongate needles along the columnar quartz grainboundaries and is particularly plentiful as small isolated crystals at and near the edges of the veins. There has been minor infilling of tubular voids between the quartz columns with barytocalcite; no other species were observed.
 Mannardite occurs as shiny jet-black elongate prismatic crystals, with an adamantine lustre; the crystals are deeply striated parallel to their elongation. The streak is white; however, depending on the pressure used and the direction in which the streak is taken, it may appear greyish as a result of the presence of a host of tiny black needles (CM 24.1.55-66).
Image

At the Brunswick No. 12 mine, Bathurst Mining Camp, Bathurst Parish, Gloucester county, New Brunswick, Canada, mannardite occurs in an orebody in faulted metasediments and iron formation, in association with edingtonite, harmotome, barytocalcite, siderite, sphalerite and quartz (HOM).

The Shiti Mine, Hanbin District, Ankang, Shaanxi, China, is a baryte mine; it is a co-type locality for mannardite and the type locality for hanjiangite (Mindat).

At the Star Mine, Theunissen kimberlite field, Theunissen, Masilonyana Local Municipality, Lejweleputswa District Municipality, Free State, South Africa, mannardite has been found in kimberlite (HOM).

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