Pseudolyonsite

pseudolyonsite

palmierite

lyonsite

piypite

Images

Formula: Cu3(VO4)2
Anhydrous vanadate, monoclinic paramorph of triclinic mcbirneyite
Crystal System: Monoclinic
Specific gravity: 4.749 calculated
Hardness: 2 to 3
Streak: Reddish brown
Colour: Dark red with a brownish tint to black
Environments

Fumeroles

Pseudolyonsite was approved in 2009; to date (January 2023) it has been reported only from the type locality.

Localities

At the type locality, the Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia, pseudolyonsite was found among other fumarolic minerals in the Yadovitaya fumarole. The scoria cones formed during the Tolbachik Fissure Eruption in 1975; in 2009, 34 years after the eruption, there were still several gas vents with temperatures of 200 to 480oC at the top parts of the cones. The rocks there are altered by HF- and HCl- rich gases and are often covered by a fluoride-rich crust. Pseudolyonsite, together with most other minerals discovered on Tolbachik, occurs in cavities from several centimetres to 1.5 m in size under the surface crust.
Pseudolyonsite is one of the rarest minerals here. It is commonly present as an overgrowth on acicular piypite. The pseudolyonsite crystals occur as needles that are 5 to 20 µm across and up to 0.5 mm in the length, which sometimes produce parallel intergrowths, sprays or openwork clusters up to 2 mm in size. The mineral’s dark red crystals are clearly visible on the overall green background of copper sulphates. Pseudolyonsite was most likely deposited at a temperature ranging from 200 to 300oC. It appears that it occurred during one of the latest stages of deposition.
Closely associated minerals are piypite, palmierite, lyonsite and hematite. Pseudolyonsite overgrows aggregates of piypite, and it is itself rarely overgrown by minute crystals of piypite, palmierite and hematite. Other spatially related minerals are magnetite, aphthitalite, langbeinite, filatovite, lammerite, vergasovaite, rutile and native gold (EJM 23.3.475-481).

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