Xenotime-(Gd)

xenotime-(Gd)

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Formula: Gd(PO4)
Phosphate of gadolinium, xenotime group, tetragonal paramorph of monoclinic monazite-(Gd)
Crystal System: Tetragonal
Specific gravity: 5.55 calculated for the ideal formula and 5.26 for the empirical formula
Environments

Hydrothermal environments

Xenotime-(Gd) is a new mineral, approved in 2022 and to date (December 2024) reported only from the type locality.

Localities

At the type locality, the Zimná Voda uranium occurrence, Prakovce, Gelnica District, Košice Region, Slovakia, xenotime-(Gd) forms rare crystal domains (≤20 μm, usually ≤10 μm in size) in gadolinium-rich xenotime-(Y) crystals (≤100 μm in size), in association with monazite group minerals, uraninite, fluorapatite and uranyl arsenates–phosphates. The hydrothermal REEuraniumgold mineralisation occurs in a quartzmuscovite vein, hosted in Palaeozoic (538.8 to 251.9 million years ago) phyllites near exocontact with Permian (298.9 to 251.9 million years ago) granites.
This exotic REE signature and precipitation of gadolinium-bearing minerals is a product of selective complexing and enrichment in middle REE in low-temperature hydrothermal fluids by alteration of uraninite, brannerite and fluorapatite on a micro-scale. The existence of xenotime-(Gd) and monazite-(Gd) is the first naturally documented dimorphism (paramorphism) among REE phosphates. In addition, xenotime-(Gd) is only the third approved gadolinium-dominant mineral, after lepersonnite-(Gd) and monazite-(Gd) (MM 88.5.613-622).

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