Armalcolite

armalcolite

Images

The name is in honour of the first three astronauts who traveled to Earth's Moon, Neil ARMstrong, Edwin ALdrin and Michael COLlins, the Apollo 11 astronauts who collected the type samples in 1969 (Mindat).

Formula: (Mg,Fe2+)Ti2O5
Valence: (Mg,Fe2+)Ti4+2O5
Oxide of magnesium, ferrous iron and titanium, pseudobrookite group, forms a series with pseudobrookite
Crystal System: Orthorhombic
Specific gravity: 4.94 measured, 4.64 calculated
Hardness: 5
Colour: Grey
Environments

Igneous environments
Derived from the mantle
Lunar environments

Armalcolite typically is formed at low pressures and high temperatures; in titanium-rich basalts and microbreccias of lunar samples; in salic (containing large amounts of silica and alumina) volcanics; rarely in granite pegmatites; in ultramafic rocks, lamproites, kimberlites; in terrestrial impact craters; in inclusions in a carbonaceous chondrite (HOM).

Localities

There are two co-type localities, Disko Island, Qeqertalik, Greenland and Tranquillity Base (Apollo 11 landing site), Mare Tranquillitatis, The Moon.

At Disko Island, Qeqertalik, Greenland, armalcolite is associated with ilmenite, Fe–Ti oxides, iron and graphite (HOM).

Mexico. Aluminous armalcolite has been found in two sillimanite-bearing xenoliths that were recently exhumed from the lower crust of central Mexico. The occurrence of armalcolite is unusual in crustal paragneiss because most terrestrial armalcolite occurs in volcanic rocks that are derived from partial melting in the Earth’s mantle. Textures suggest that armalcolite is a late product formed by the reaction:
rutile + ilmenitess = armalcolitess
TiO2 + Fe2+TiO3 = (Mg,Fe2+)Ti2O5
during rapid transport of the xenoliths to the surface. Indications are that armalcolite is stable in the crust at 900°C to 1200°C (AM 80.810–822).

At Kimberley, Sol Plaatje Local Municipality, Frances Baard District Municipality, Northern Cape, South Africa, armalcolite is associated with rutile and ilmenite (HOM).

At Smoky Butte (Smoky Butte Lamproite), Garfield County, Montana, USA, armalcolite is associated with phlogopite, analcime and diopside (HOM).
Armalcolite from Smoky Butte - Image

At Tranquillity Base (Apollo 11 landing site), Mare Tranquillitatis, The Moon, armalcolite occurs as subhedral to anhedral grains to 300 µm across in titanium-rich basalt and microbreccias of lunar samples, formed at low pressures and high temperatures (Mindat).
Armstrong, Aldrin and Collins - Image

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