Bytízite

bytizite

chameanite

bukovite

pribramite

Images

Formula: Cu3SbSe3
Sulphosalt, copper-, antimony- and selenium- bearing mineral
Crystal System: Orthorhombic
Specific gravity: 6.324 calculated for the empirical formula
Hardness: 2 to 3
Colour: Steel-grey
Environments

Hydrothermal environments

Bytizite is a relatively new mineral, approved in 2016.

Localities

The type locality is the Mine dump, Uranium Mine No. 16, Háje, Příbram District, Central Bohemian Region, Czech Republic. In this ore district, there are four main mineralisation stages:
(1) siderite–sulphides
(2) calcite
(3) calciteuraninite
(4) calcite-sulphides
Selenide mineralisation occurs in close association with uraninite of the calciteuraninite mineralisation, but selenides are always younger than uraninite. It is uncertain whether the selenides at Príbram formed at the end of the calciteuraninite stage, or at the beginning of the following calcite–sulphides stage.
The first selenide found there was clausthalite, reported in 1986; subsequently, eight more selenides were found in 2004. Since 2005, many more specimens of a selenide-containing gangue have been found in the dump material. This material contains a very rich selenide assemblage, including bytízite.
The selenium-uranium mineralisation is of low-temperature hydrothermal origin and is confined to calcite veins with a thickness varying from tens of centimetres to several metres. The main ore is represented by uraninite, while younger pyrobitumen predominates in deeper parts of the deposit. Macroscopically, bytízite forms a substantial part of up to 1 mm large steel-grey grains in a calcite vein several millimetres thick. This younger carbonate vein cuts perpendicularly through an older calcite vein containing common umangite and uraninite, so umangite is unequivocally older than other selenides in the association. Bytízite forms anhedral grains enclosing other coexisting selenides such as chaméanite, bukovite, príbramite, eskebornite, crookesite and giraudite-(Zn). Therefore, bytízite appears to be the youngest selenide in the association. Hakite and tetrahedrite also occur, probably as relatively late phases.
Bytízite forms anhedral grains 10 to 40 µm across, growing together in aggregates up to 300 µm across. The mineral is steel-grey in colour and opaque with a metallic lustre. No cleavage or fracture were observed. (MM 82.1.199–209).
Bytízite from Příbram - Image

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