Coquandite

coquandite

klebelsbergite

peretaite

valentinite

Images

Formula: Sb3+6+xO8+x(SO4)(OH)x(H2O)<1-x (x = 0.3)
Sulphate, antimony-bearing mineral
Crystal System: Triclinic
Specific gravity: 5.78 calculated
Hardness: 3 to 4
Streak: White
Colour: Colourless
Luminescence: No fluorescence observed under short wave or long wave UV
Environments

Sedimentary environments
Hydrothermal environments

Coquandite occurs in association with klebelsbergite, peretaite, valentinite, senarmontite, stibiconite, stibnite, sulphur, gypsum and quartz (HOM).

Localities

There are two co-type localities, the Pereta Mine, Scansano, Grosseto Province, Tuscany, Italy, and the Lucky Knock Mine, Okanogan County, Washington, USA.

At the Pereta Mine, Scansano, Grosseto Province, Tuscany, Italy, the main geological formations outcropping in the area are, from bottom to top, the 'Calcare Cavernoso' limestone, the 'Macigno' sandstone, and sands and clays of the 'Neoautoctono Toscano'. A stibnite vein with quartzitic gangue fills a fracture in the limestone, which appears to be thoroughly silicised. Coquandite usually occurs as white powdery masses enbedded between the needles of columnar stibnite, or as thin crusts with a pearly lustre. It appears sometimes as spheroidal knobs of feathery aggregates of silky fibres, and, rarely, as tiny flexible lamellar crystals on stibnite and quartz in cavities in the limestone. Coquandite is strictly associated with klebelsbergite and peretaite, and is also associated with valentinite, senarmontite, sulphur, gypsum and stibiconite. Like klebelsbergite and peretaite, coquandite was probably formed by the action of sulphuric acid on stibnite.
Coquandite crystals occur as tiny transparent to translucent elongated colourless individuals, that are flexible and often display an onion-skin aspect (MM 56.599-603).
Coquandite from the Pereta Mine - Image

At Le Cetine di Cotorniano Mine, Chiusdino, Siena Province, Tuscany, Italy, the environment in which coquandite was found is similar to that of Pereta. The ore at the Cetine mine consists of stibnite in small pods disseminated within the highly silicified limestone of the 'Calcare Cavernoso' formation. Coquandite, which is very rare in this locality, occurs as minute tabular crystals on stibnite or quartz, in small cavities in the limestone. The associated minerals are the same as observed at Pereta, namely strictly associated with klebelsbergite and peretaite, and also associated with valentinite, senarmontite, sulphur, gypsum and stibiconite (MM 56.599-603).
Coquandite from Le Cetine di Cotorniano Mine - Image

At the Lucky Knock Mine, Okanogan County, Washington, USA, coquandite appears as silky fibres or small platelets implanted on stibnite or stibiconite needles (MM 56.599-603).
Coquandite from the Lucky Knock Mine - Image

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