Fluoro-richterite

fluoro-richterite

Images

Formula: Na(NaCa)Mg5Si8O22F2
Inosilicate (chain silicate) with double chains, richterite root name group, sodium-calcium amphibole subgroup, w(OH,F,Cl)-dominant amphibole group, amphibole supergroup
Crystal system: Monoclinic
Specific gravity: 3.174 measured, 3.213 calculated
Hardness: 5 to 6
Streak: White
Colour: Brown to brownish red, rose-red, yellow, grey-brown, pale to dark green
Solubility:
Common impurities:
Environments

Pegmatites
Carbonatites
Metamorphic environments
Hydrothermal environments

Localities

At the Earle's Farm fluoro-richterite occurrence, Monmouth Township, Highlands East Township, Haliburton County, Ontario, Canada, crystals of fluoro-richterite to 25 cm long occur in calcite (R&M 94.5.413).
Fluoro-richterite from Earle's Farm - Image

At Kariåsen, Vesterøya, Sandefjord, Vestfold, Norway, two large pegmatite veins intruded in larvikite were exposed during blasting.
A coarse, somewhat altered pegmatite vein in the southeastern part of the worked area contains microcline (as large crystals of perthitic alkali feldspar up to 30 cm long), amphibole (“magnesio-katophorite” as large, coarse crystals up to 20 cm long), large masses of aenigmatite (as black, shiny crystals with a typical reddish streak), ferrokentbrooksite (as large brown to reddish brown masses, sometimes altered to a yellowish skeleton-like or powdery material), albite (as small crystals in cavities), zircon (as brown to whitish crystals in cavities), aegirine (as small, dark-green needle-shaped crystals in cavities), and quartz (as greyish-brown crystals up to 14 mm long in cavities with albite and epididymite).
A less-altered coarse pegmatite vein in the northeastern part of the worked area also contains microcline, “magnesio-katophorite”, aenigmatite, aegirine and albite, with the same characteristics as the other vein. Moreover, it contains riebeckite (as pale-blue fibrous masses of acicular crystals), annite (rare), zircon (as prismatic, brown crystals up to 3 cm in length, often close to “magnesio-katophorite” and aenigmatite, or as brown to yellow and whitish bipyramidal crystals up to 1 mm in cavities with albite and aegirine), chlorite (as globular crystal aggregates on aegirine and albite in cavities), pyrite (as small crystals in cavities, occurring as cubes, octahedra, pentagonal dodecahedra, and globular crystal aggregates), fluorapatite (as long colourless, white or yellow prismatic crystals in cavities, often covered by pyrite crystals on the prism faces, or white crystals up to 3 cm long in the matrix), titanite (as small, brown, striated crystals in cavities with aegirine and albite), and calcite (as well developed crystals in cavities). Other minerals found in the cavities are parisite-(Ce) (as brownish, prismatic crystals up to 5 mm long in cavities or golden-yellow crystals covered by pyrite on the prism faces, the basal faces being uncovered), pyrochlore (as brown octahedra up to 1 cm), bastnäsite-(Ce) (partly as epitactic intergrowths with parisite-(Ce) in cavities, partly as a brownish zone surrounding fluorapatite crystals up to 2 cm in matrix), magnetite (rare), hematite (as rosettes of thin tabular crystals), galena (as rare cube-octahedral crystals), molybdenite (as thin tabular crystals with a hexagonal outline up to 1 cm in size), thorite (as brownish-black metamict masses up to 3 cm), ilmenite (black, elongated, rounded crystals up to 14 mm long in an alkali feldspar matrix), epididymite (as colorless, tabular, elongated crystals up to 5 × 2 mm), britholite-(Ce) (in reddish-brown zones surrounding fluoroapatite), allanite-(Ce) (as aggregates of dark reddish-brown crystals up to 1 mm), grossular (as green crystals up to 1 mm), andradite (as green dodecahedra up to 1 mm), arsenopyrite (as crystal aggregates up to 0.5 mm), bertrandite (as colorless, square tabular crystals up to 0.7 mm), elpidite (as small pale-brown crystal aggregates, always somewhat altered), helvine (as aggregates of numerous sub-parallel crystals up to 2 mm in a cavity with elpidite, aegirine and quartz), monazite-(Ce) (as small brown crystals), zirconolite-3O (as black, prismatic crystals up to 2 mm long in an alkali feldspar matrix) and sphalerite (as reddish-brown crystals up to 0.6 mm).
The sodium-calcium amphiboles have been ascribed to a late stage of the pegmatite evolution, and sodium amphiboles (rare, but present at Kariåsen) are considered to be a secondary hydrothermal phase (CM 53.2.285-294).

At the type locality, Pit No. 97, Miass, Chelyabinsk Oblast, Russia, fluoro-richterite occurs as a rock-forming component in fenites (accompanied by microcline, albite and phlogopite), carbonatites and metasomatic rocks (accompanied by calcite, dolomite, phlogopite, magnetite, pyrochlore, zircon, apatite, pyrrhotite, pyrite and ilmenite) (AM 80.404-405).
Crystals are elongated, up to 10 cm long (Mindat).
Fluoro-richterite from Pit No. 97 - Image

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