Gladiusite

gladiusite

catapleiite

rimkorolgite

strontiowhitlockite

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Formula: Fe3+2Fe2+4(PO4)(OH)11.H2O
Hydrated phosphate
Crystal System: Monoclinic
Specific gravity: measured 3.11, calculated 3.08
Hardness: 4 to 4½
Streak: Olive-green, changing colour to brownish red in 10 to 12 hours
Colour: Dark green, almost black, red-brown, brownish
Luminescence: No fluorescence under UV
Solubility: Soluble in hydrochloric acid after several hours at room temperature
Environments

Carbonatites
Hydrothermal environments

Gladiusite was approved in 1998 and to date (December 2022) has been recorded only from the type locality.

Localities

At the type locality, the Kovdor Massif, Murmansk Oblast, Russia, the massif was emplaced into a metamorphic sequence comprised mostly of amphibole-biotite gneiss. An ultramafic core (olivinite, pyroxenite and diopsideolivine rocks) is surrounded by turjaite, melilitolite, phlogopite-bearing diopsideolivine rock, garnetamphibolemonticellite rock, nepheline pyroxenite, phoskoritecarbonatite and carbonate–fluorapatite-cemented breccias, with outer zones of alkaline rocks (jacupirangite, ijolitemelanocratic nephelinolite). A well-defined fenite zone surrounds the massif.
The phoskoritecarbonatite complex was emplaced into pyroxenites and ijolites, and is bordered by a a fine-grained apatiteforsterite metasomatic rock. Postmagmatic re-activation of the fault has caused extensive rock deformation, accompanied by an influx of hydrothermal fluids from the cooling phoskorite and carbonatite. As a result, the hydrothermal assemblages superimposed on the dolomite carbonatite contain a variety of rare minerals.
Gladiusite is confined to hydrothermal assemblages from vugs in deformed and mineralised dolomite carbonatite. The order of crystallisation is as follows: primary pyrrhotite and fluorapatitedolomitepyrochloremagnetite (type I) or pyriterutileternovite-like phase → catapleiiterimkorolgitebobierritecollinsitejuonniitestrontiowhitlockitepyrrhotite (type II)gladiusitestrontium-bearing collinsitemagnetite-(type II) → chloritedolomite (the minerals associated with gladiusite are in italics). Gladiusite is not associated with other hydrous iron phosphates in these hydrothermal assemblages. Vivianite and strengite occur in the upper horizons of the phoskoritecarbonatite complex.
Gladiusite occurs as acicular masses and as freestanding radiating clusters of arrow-head crystals; clusters do not exceed 2 mm in diameter. Acicular crystals vary from 0.5 to 7 microns thick and from 10 to 500 microns long (CM 38.1477-1485).

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