Goldichite

goldichite

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Formula: KFe3+(SO4)2.4H2O
Hydrated sulphate
Crystal System: Monoclinic
Specific gravity: 2.43 measured, 2.461 calculated
Hardness: 2½
Streak: White
Colour: Pale yellowish green
Environments

Sedimentary environments
Fumeroles rarely

Localities

At the Santa Bárbara sulphur mine, El Palmar hot springs, Cerros de Santa Bárbara, Santa Bárbara Department, Jujuy Province, Argentina, the sulphur prospect is hosted by calcareous sandstone and yellow limestone. These rocks are argillised (altered to clay minerals) in the mineralised zone and contain disseminated sulphur in rhombic crystals, gypsum in milimetric veinlets and lenses, and a suite of sulphates composed of voltaite, metavoltine, hexahydrite, alunogen, sideronatrite, ferrinatrite, krausite, halotrichite and goldichite. This assemblage occurs in underground works where, at the time of collection, in the floor of one of the workings, two fumarolic vents 10 cm in diameter were dispersing a CO2-rich vapour phase at a temperature of 40o to 50oC. The fumarolic vents are surrounded by a soft mass composed of halotrichite and alunogen spotted with crystals of voltaite and krausite. The other sulphates, including goldichite, occur on the argillised (altered to clay minerals) rock that forms the walls of the galleries (CM 33.1059-1062).

At the type locality, the Dexter No. 7 Mine, Calf Mesa Mining District, Emery county, Utah, USA, shales and mudstones form a steep slope below a cliff. Directly below the ore horizon, and extending down over the slope, is a talus breccia composed of fragments of conglomerate. A trench has been cut into this talus directly below the workings, and it is here that the sulphates are found cementing the talus fragments. The minerals of this suite, in addition to goldichite, are coquimbite, halotrichite, römerite, alunogen, copiapite, melanterite, fibroferrite, voltaite, butlerite, parabutlerite, chalcanthite and diadochite. The essential minerals of the uranium deposit are metazeunerite, pyrite and chalcopyrite.
Goldichite occurs as small laths in radiating clusters and as encrustations of minute crystals in the near surface zone of the talus. It is closely associated with platy masses of white alunogen, purple crystals of coquimbite and bright yellow, small crystals of copiapite (AM 40.469-480).

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