Kozyrevskite

kozyrevskite

ericlaxmanite

langbeinite

urusovite

Images

Formula: Cu4O(AsO4)2
Anhydrous arsenate, paramorph of ericlaxmanite
Crystal System: Orthorhombic
Specific gravity: 4.934 calculated
Hardness: 3½
Streak: Very light green
Colour: Bright grass green to light yellowish green
Environments

Fumeroles

Kozyrevskite is a relatively new mineral, approved in 2013 and to date (January 2023) reported only from the type locality.

Localities

At the type locality, the Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia, ericlaxmanite and kozyrevskite occur in the same mineral assemblage and are associated intimately with each other; they are also associated closely with the other alkali-free arsenates urusovite, lammerite, paralammerite, popovite and alarsite, and sometimes with the sodium- or potassium-bearing arsenates johillerite, bradaczekite, shchurovskyite and dmisokolovite. Other associated minerals are tenorite, hematite, aphthitalite, langbeinite, anhydrite, arsenic-bearing orthoclase, copper-rich gahnite and, sporadically, calciolangbeinite, arcanite, wulffite, krasheninnikovite, steklite, palmierite and OH-free fluoborite. All these minerals form complex, polymineralic, sometimes very rich, incrustations up to 0.5 cm thick on the surface of basalt scoria in pockets from 0.3 to 0.8 m deep under the present day surface. The temperature measured inside these pocketsin July 2013 was 360 to 380oC. It is considered that all listed minerals were deposited directly from the gas phase or were formed as the result of gas-rock interactions at temperatures of not less than 380oC.
Kozyrevskite forms prismatic to long prismatic, typically divergent crystals up to 0.02 x 60.05 x 60.3 mm3 in size and their radiating, sheaf-, bush- or rosette-like clusters up to 0.3 mm across. Abundant crystals and crystal clusters or, rarely, thin crusts of kozyrevskite occur on incrustations consisting of langbeinite and arsenic-bearing orthoclase, or on volcanic scoria. Kozyrevskite is one of the latest copper arsenates in the Arsenatnaya paragenesis, overgrowing not only urusovite and lammerite but also ericlaxmanite (MM 78.1553–1569).

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