Rusinovite

rusinovite

wadalite

tazheranite

gehlenite

Images

Formula: Ca10(Si2O7)3Cl2
Sorosilicate (Si2O7 groups)
Crystal system: Orthorhombic
Specific gravity: 2.93 measured, 2.931 calculated
Hardness: 3 to 4
Streak: White
Colour: White
Environments

Volcanic igneous environmenta
Metamorphic environments

Localities

At the NW slope, Shadil-Khokh volcano, Kel’ volcanic area, Greater Caucasus Mountain Range, South Ossetia, Georgia, rusinovite was found in pyrometamorphic rock in an altered carbonate-silicate xenolith, about 2 m across, within dacite lava. This xenolith is composed of minerals characteristic of sanidinite facies metamorphism, such as spurrite, larnite, gehlenite, merwinite, bredigite, rondorfite and srebrodolskite. Rusinovite occurs as relatively large elongated crystals, 100 to 200 microns in length, with a characteristic macroscopic brown-orange colour, in small veins, up to 0.5 cm wide, encountered at the exocontact zone (on the dacite side of the contact) of the xenolith. Rusinovite was found also at the endocontact zone (on the xenolith side of the contact) of strongly altered dacite.
The presence of microzonation at both endocontact and exocontact zones is reflected in the distribution of minerals with different Ca:Si ratios.
At the endocontact (xenolith side of the contact), there are four zonation zones; the numbering is according to the Ca:Si ratio increasing.
The first zone is dacite, consisting of enstatite, albite phenocrysts and quartz enclosed in the fine-grained aggregate of diopside, plagioclase and Na–K feldspar. Visible zonation of enstatite is caused by variations of minor Fe substitutions in composition. Ilmenite occurs as an accessory mineral.
The second zone is composed of massive gehlenite.
The third zone is comprised mostly of rusinovite and gehlenite; hydroxylellestadite and wollastonite are noted rarely.
The fourth zone is represented by strongly altered rock, mainly composed of secondary Ca–Si hydrosilicates, rusinovite, cuspidine and rondorfite.
Another type of zonation is observed at the dacite-xenolith boundary (exocontact, dacite side).
In the first zone the altered dacite is composed of diopside, enstatite, plagioclase phenocrysts and quartz. the matrix is a fine-grained aggregate of plagioclase; ilmenite, titanite, apatite and pyrite occur as accessory minerals.
In the second zone towards the xenolith, wollastonite and andradite are the main minerals, and the accessory phases include cuspidine, gehlenite and wadalite.
In the third zone, rusinovite occurs as a major component together with cuspidine. Wollastonite is present, but not as commonly as in the previous zone. Cl-bearing hydroxylellestadite, gehlenite, magnesioferrite and rondorfite are also noted.
The fourth and last zone is a strongly altered xenolith part composed mostly of secondary Ca-hydrosilicates with the relics of rondorfite, larnite, cuspidine and merwinite (Minerals 8.9.399).

At the Bellerberg volcano (Caspar quarry), Vordereifel, Mayen-Koblenz, Rhineland-Palatinate, Germany, rusinovite was found in pyrometamorphic rock. In the active Caspar quarry, within leucite tephrite, small Ca-rich xenoliths can be found, formed at high temperatures and low pressure. The main part of the xenolith is composed of larnite, gehlenite, rondorfite, Cl-bearing hydroxylellestadite, spurrite and secondary Ca-hydrosilicates. Perovskite, hematite, cuspidine, a kerimasite-like garnet, andradite and pyrite with chalcopyrite intergrowths also occur here.
In addition to these minerals, the lighter part of the rock also contains rusinovite, wollastonite, chalcopyrite, baghdadite and lakargiite. Aggregates of rusinovite can reach up to 200 microns in size. They contain a lot of inclusions of minerals including gehlenite, chlorine-bearing ellestadite, perovskite and hematite, mainly, and strongly hydrated zones (Minerals 8.9.399).

At the type locality, Xenolith no. 3, Lakargi Mountain, Upper Chegem volcanic caldera, Chegemsky District, Kabardino-Balkaria, Russia, rusinovite was found in the altered carbonate-silicate xenolith within ignimbrites. The xenolith no. 3 is also the type locality of calcio-olivine, megawite and toturite. Rusinovite was detected within a thin endocontact zone (on the xenolith side of the boundary) of skarn which replaced ignimbrite. Rusinovite forms fibres intergrown to spherulites displaying in thin section bright interference colours. Detailed investigation of skarn zonation revealed a rusinovite zone, composed of fine needles and fibrous aggregates of rusinovite, often with inclusions of numerous wadalite grains. Relics of earlier, high temperature, skarn minerals, such as larnite, rondorfite, rankinite, pavlovskyite, cuspidine, tazheranite, baddeleyite, garnet minerals of the kerimasite - kimzeyite - toturite series, lakargiite, perovskite and magnesioferrite are found.
Low-temperature alteration is evidenced by hillebrandite, afwillite, tobermorite, grossular-katoite, hydrocalumite and ettringite group minerals. Trabzonite and jennite crystallised after rusinovite and wadalite is replaced by grossular-katoite. In several cases, fibrous pseudomorphs of rusinovite after wollastonite have been found (EJM 23.837-844).
Rusinovite from the Lakargi Mountain - Image

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