Sanguite

sanguite

belloite

avdoninite

eriochalcite

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Formula: KCuCl3
Chloride
Crystal System: Monoclinic
Specific gravity: 2.86 measured, 2.88 calculated
Hardness: 3
Streak: Reddish orange
Colour: Bright red
Environments

Fumeroles

Sanguite is a relatively new mineral, approved in 2013 and to date (November 2023) reported only from the type locality.

Localities

The type locality is the Glavnaya Tenoritovaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia. The Second scoria cone is a monogenetic volcano formed in 1975. Gas vents belonging to the Glavnaya Tenoritovaya fumarole fumarole occupy an area of 1.7 x 4.2 m2. In the main part of this area, temperatures of 350 to 360°C were measured at a depth of approximately 20 cm below the surface. Major minerals formed in this oxide-sulphate zone are hematite, tenorite, euchlorine, dolerophanite, chalcocyanite, anglesite, krasheninnikovite and anhydrite (listed in order of distribution).
The rich chloride mineralisation occurs in the outer, moderately hot (110°C) zone on the northern flank of the fumarole. Chlorides are major constituents of this zone, represented by belloite, avdoninite, eriochalcite, sylvite, halite, carnallite, mitscherlichite, sanguite, chrysothallite, romanorlovite and mellizinkalite. Other minerals in this zone are gypsum, chlorothionite, kainite, sellaite, and earlier hematite, tenorite and chalcocyanite. In this sulphate-chloride zone, OH- and H2O- bearing minerals play a significant role, unlike in the hottest oxide-sulphate zone (350 to 360°C), in which only anhydrous minerals are present.
Sanguite is common in the sulphate-chloride zone of the fumarole. Some areas contain up to 15 vol% of this mineral. Sanguite forms prismatic crystals in cavities; the crystals are up to 1 mm long and up to 0.2 mm thick, typically combined in groups, dense clusters or crusts. Some sanguite crusts are up to several dozens of cm2 in area. Granular aggregates up to 1 mm across in polycomponent chloride incrustations are also observed. Some cavities up to 0.5 mm in diameter in basalt scoria are completely filled by sanguite (CM 53.4.633-641).

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