Chlorargyrite

chlorargyrite

smithsonite

bayldonite

cerussite

Images

Formula: AgCl
Chloride of silver, chlorargyrite group
Crystal System: Isometric
Specific gravity: 5.5 to 5.6 measured, 5.57 calculated
Hardness: 1½
Streak: White to grey
Colour: Colourless, white, yellowish, brownish, grey, black
Melts at 455°
Common impurities: I
Environments:

Hydrothermal environments

Chlorargyrite is a secondary mineral found in the oxidation zone of silver deposits, especially in arid regions, and in epithermal (low temperature) veins. It is found associated with native silver, cerussite and other secondary minerals.

Localities

At the Broken Hill district, Yancowinna county, New South Wales, Australia, the deposit originally formed in a shallow lake or submarine rift and now comprises an intensely granulite and upper amphibolite facies metamorphosed and deformed sequence of sedimentary and volcanic rocks, and minor iron-rich and layers. Quartz-feldspar gneiss probably originated from felsic volcanic rocks and associated granitic intrusions, while amphibolites reflect metamorphosed mafic magmas originally emplaced as flows and associated intrusions. Subaqueous hydrothermal precipitation involving ore fluids from crustal, magmatic, evaporitic, and possibly lacustrine sources produced metal-rich deposits. Prolonged oxidation and weathering of the sulphide-rich orebodies in the near-surface environment produced a zone greatly enriched in silver and lead and many attractive, well-crystallised secondary minerals. This oxidised zone has long been removed by mining; current operations access the deeper, primary sulphide-rich orebodies (R&M 97.1.16-26).
Chlorargyrite occurs in vuggy coronadite with goethite, sometimes associated with smithsonite. It is also found with cerussite, dolomite and malachite. At deeper levels it is a late-stage mineral in the arsenate zones, associated with carminite and members of the segnitite to beudantite series (AJM 3.1.34).

Chlorargyrite from Broken Hill - Image

At Johanngeorgenstadt, Erzgebirgskreis, Saxony, Germany, in the 17th and 18th centuries, large amounts of chlorargyrite were found in the upper parts of the ore veins. It occurred as waxy white to glittery brown, green, bluish, grey and almost black masses, as bud-like to fibrous, hairlike forms, and in sharp, cubic crystals. Among the associated minerals were limonite and a little palygorskite. Chlorargyrite was also commonly found intergrown with cerussite, as at the Neujahr Maassen mine.
In the final period of mining—from 1945 to 1958—during which only uranium ores were produced, isolated unworked ore veins were discovered, and chlorargyrite was found in their oxidation zones.
There remains to be mentioned a strange fluid-like to gelatinous type of chlorargyrite referred to by miners as buttermilk ore or moon milk. It is a mixture of chlorargyrite and other minerals that takes a viscously fluid form. Chlorargyrite was mined in fair quantities from the upper portions of ore veins, having been deposited there predominantly by precipitation of silver chloride from solutions. Initially it formed viscous suspensions which thickened gradually to paste-like deposits and finally to more or less solid bodies. Today, “buttermilk ore” is among the greatest rarities (MinRec 55.5.593-595).
Chlorargyrite from Johanngeorgenstadt - Image

The type locality is the Marienberg mining district, Erzgebirgskreis, Saxony, Germany.

At the San Rafael Mine, Quartz Mountain camp, Lodi Mining District, Lodi Hills, Nye County, Nevada, USA, chlorargyrite and bromargyrite occur sparingly, associated with mimetite, anglesite and bayldonite (R&M 85.6.516).

Chlorargyrite from the San Rafael Mine - Image

At the Tintic Mining District, Juab County, Utah, USA, probably the most common silver mineral of the District, chlorargyrite, has been found in many of the mines, particularly where galena and other lead minerals are more common. At the Trixie mine in the East Tintic chlorargyrite occurs directly with hessite, native silver and native gold. It is most commonly found as brown smears that look like dirt; however, crystallized chlorargyrite has also been found at the Trixie mine.
At the nearby Tintic Standard mine, chlorargyrite rich in bromine has also been found, as solid masses up to 5 cm in size (MinRec 55.2.190-192).

Chlorargyrite from the Tintic Mining District - Image

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