Durangite

durangite

cassiterite

wickmanite

cristobalite

Images

Formula: NaAl(AsO4)F
Arsenate, tilasite group, forms series with tilasite and with maxwellite
Crystal System: Monoclinic
Specific gravity: 3.94 to 4.07 measured, 3.616 calculated
Hardness: 5½
Streak: Cream-yellow
Colour: Light to dark orange-red, red, green; orange-yellow in artificial light
Luminescence: Not fluorescent under either short wave or long wave UV
Solubility: Insoluble in aqua regia, slowly soluble in either HCI or HNO, readily soluble in hot, concentrated sulphuric acid
Magnetism: Not magnetic
Common impurities:
Environments

Volcanic igneous environments
Pegmatites

Durangite occurs in veins in alkalic rhyolite and in placers derived therefrom, also in pegmatite dikes in granite. Associated minerals include cassiterite, hematite, topaz, ilmenite, tantalite, wickmanite, beudantite, mimetite, fluorite, tridymite, cristobalite, quartz, amblygonite, chalcedony, zeolites and clay minerals (HOM).

Localities

At the type locality, the Barranca Mine, Coneto de Comonfort, Coneto de Comonfort Municipality, Durango, Mexico, durangite occurs in tin-bearing veins associated with cassiterite, hematite (including the variety specularite), quartz, tridymite, cristobalite, opal, chalcedony, fluorite, topaz, mimetite, sanidine, montmorillonite and zeolites. It has also been reported in residual and alluvial placer deposits derived from the tin veins.
The only major difference between the Black Range (see below) and Coneto assemblages is the presence of beudantite in the Black Range as an alteration product and coexisting mineral with durangite, rather than mimetite, which is found associated with the durangite at Coneto (CM 23.2.241-246).
Durangite from the Barranca Mine - Image

The Black Range, New Mexico, USA, hosts the 74 Draw deposits and Boiler Peak, both in Sierra County. In these Black Range locations, durangite occurs as small grains and aggregates in veins and veinlets several centimetres in width within zones of alteration in an alkali rhyolite host-rock. The veins form reticulate networks 3 to 100 metres wide. The minerals in these veins include, in generalised paragenetic sequence, with some minerals occurring in multiple generations, hematite (much of it specularite), wood tin, , cassiterite, wood tin, durangite, hematite, silica paramorphs quartz, tridymite and cristobalite, durangite, beudantite, fluorite, cristobalite, pink to white dioctahedral smectite, todorokite, and disordered, red-brown dioctahedral smectite. A red-brown to orange-red Ca-Fe clinopyroxene was found associated with the durangite at Seventyfour Draw but was not found at Boiler Peak.
Durangite from the Black Range is pale yellow-orange to medium orange-red and is clear to semi-translucent where fresh. Individual crystals reach 2 mm in maximum dimension, but most are less than 0.5 mm across. Durangite from all localities has a vitreous lustre, a pale yellow streak and shows irregular and conchoidal fracture and one good cleavage (CM 23.2.241-246). At 74 Draw deposits, Sierra County, New Mexico, USA, the durangite is generally pale to medium yellow-orange or orange rather than orange-red. Individual grains are 0.5 mm across or more. The associated minerals are the same as described for Boiler Peak (see below) except that the white, fine-grained mixture of fluorite, montmorillonite and cristobalite is less abundant here. Fluorite also occurs locally as clear, grey, discrete botryoidal masses. Much of the final generation of cassiterite is in the form of rounded clumps of slender, almost white, acicular needles. Some of these clumps are several millimetres across; individual needles of cassiterite are as much as 200 pm long but only 10 pm or so wide. Euhedral, prismatic crystals and some euhedral, squat, tabular crystals of red-brown to orange-red or orange clinopyroxene, some of which exceed 2 mm in width, are intermixed with the cassiterite - fluorite - hematite - durangite association (CM 23.2.241-246).

At Boiler Peak, Sierra County, New Mexico, USA, durangite occurs as pale yellow to medium reddish orange grains and aggregates. The grains are as much as 0.5 mm across, and the aggregates up to 2 mm across. The bulk of the durangite occurs as etched and altered material within the mineralised veinlets. Some grains are very clear, unfractured and unaltered. Deposition of the durangite was contemporaneous with deposition of crystalline cassiterite and wood tin, hematite, and the silica polymorphs. The durangite encloses and is enclosed by these minerals. Extremely fine-grained white fluorite, admixed with cristobalite and dioctahedral montmorillonite, was subsequently deposited. Yellow-green, fine-grained beudantite was deposited still later; some of the beudantite apparently crystallised along with the durangite, and some is pseudomorphic after it. The final products of deposition within the open spaces of the veins are black, sooty, fine-grained lead-rich todorokite and sticky, deep red-brown, disordered dioctahedral smectite containing fragments of the previously mentioned minerals (CM 23.2.241-246).

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