Perchiazziite

perchiazziite

calcite

magnetite

cobalt

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Formula: Co2(CO3)(OH)2
Carbonate of cobalt, rosasite group
Crystal System: Monoclinic
Specific gravity: 3.970 calculated for the empirical formula
Hardness: 4
Streak: White
Colour: Orange-pink
Luminescence: Not fluorescent under long wave, medium wave or short wave UV
Solubility: Soluble in cold hydrochloric or nitric acid with effervescence
Environments

Metamorphic environments

Perchiazziite is a new mineral, approved in 2023 and to date reported only from the type locality.

Localities

The type locality, the Mt. Ramazzo Mine, Borzoli, Genoa, Genoa, Liguria, Italy, is located in the Sestri-Voltaggio ophiolitic complex, which is hosted in serpentinised ultramafic rocks close to the contact with pillowed dolerite. The primary ores are mainly pyrite, pyrrhotite, chalcopyrite, hematite and magnetite. They have undergone supergene alteration, resulting in the presence of many secondary minerals, including sulphides such as covellite and digenite, oxides and hydroxides such as opal, goethite and heterogenite, carbonates such as azurite, artinite, hydromagnesite and nesquehonite, sulphates such as brochantite, chalcanthite, epsomite, gypsum and melanterite, and silicates such as chrysocolla. The Monte Ramazzo Mine is also the type locality for ramazzoite, and it is also known as an occurrence of the minerals of the rosasite group, including malachite, kolwezite and mcguinnessite, as well as perchiazziite.
Perchiazziite occurs as globular aggregates up to 0.1 mm in diameter, composed of very thin fibres. These develop on a matrix composed mostly of goethite and magnetite, in association with calcite and cobalt-bearing malachite. Aggregates of perchiazziite are pale orange-pink on their outer surfaces but white in thin section. It is translucent with a white streak and silky lustre.
Perchiazziite is of supergene origin, possibly having been formed as a result of the oxidation of cobalt-bearing sulphides (pyrite, chalcopyrite and pyrrhotite), hydroxides (heterogenite), and carbonates (spherocobaltite), which occur in serpentinite rocks (CJMP 62.2.369-378).

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