Rozenite

rozenite

melanterite

halotrichite

jarosite

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Formula: Fe2+(SO4).4H2O
Hydrated sulphate, rozenite group
Crystal System: Monoclinic
Specific gravity: 2.293 measured, 2.29 calculated
Hardness: 2 to 3
Streak: White
Colour: Colourless to white, pale green
Solubility: Soluble in water
Environments

Sedimentary environments
Hydrothermal environments

Rozenite is an uncommon secondary mineral, at or below 21oC under low humidity, formed directly from copper-free melanterite, which is itself an alteration product of pyrite or marcasite. Rozenite also occurs as a post-mining product, in lake-bed sediments and in coal seams. Associated minerals include melanterite, epsomite, jarosite, gypsum, sulphur, pyrite, marcasite and limonite (HOM, Mindat).

Localities

At the Francon quarry, Montreal, Quebec, Canada, rozenite is relatively rare, and is found as white powdery coatings and globules on oxidised marcasite and pyrite; it is occasionally associated with natrojarosite and rarely with halotrichite (Minrec 37.1.43).

At the Sydney coalfield, Cape Breton county, Nova Scotia, Canada, hydrated sulphates associated with the decomposition of pyrite and copper-iron sulphides occur in coal in contact with the atmosphere. Melanterite, rozenite, epsomite, pickeringite, halotrichite, aluminocopiapite and sideronatrite were identified from coal seams and mines in the coalfield (CM 16.17-22).

At the type locality, Ornak Mountain, Tatra County, Lesser Poland Voivodeship, Poland, rozenite was found as efflorescences on weathered gneiss containing pyrite, and in an old gallery of the "Staszic" pyrite mine at Rudki, Poland, where air temperatures were close to 30oC. At both places it was probably formed by the dehydration of melanterite (AM 46.242).

At the Clear Creek claim, Goat Mountain, New Idria Mining District, San Benito county, California, USA, white coatings of rare rozenite on cinnabar have been identified (Minrec 36.4.355).

At the Dolliver state park, near Fort Dodge, Webster county, Iowa, USA, abundant sulphate efflorescences on sandstone consist of halotrichite, szomolnokite and rozenite. Melanterite may occur in place of the lower hydrate, rozenite, during times of high humidity (CM 11.958-970).

At abandoned coal strip mines at Sandy Run, Brown township, Vinton county, Ohio, USA, samples of altered pyrite were collected from an abandoned mine dump. The samples were encrusted either with masses of pale green fibres, or with extremely fine white powder, or with a mixture of both. The fibrous material is melanterite and the remaining material is a mixture of melanterite, rozenite and halotrichite. Whether melanterite or rozenite is the stable phase at any place or time depends on the temperature and humidity. At humidity above about 95% the melanterite deliquesces and becomes liquid.

Rozenite melanterite stability diagram





















(AM 50.1457-1461).

At the North Mesa 5 Mine, North Mesa Mine group, Temple Mountain, San Rafael Mining District, Emery county, Utah, USA, rozenite occurs in a silicified tree that has a rim of coal around it, associated with orthominasragrite, anorthominasragrite, minasragrite, bobjonesite, szomolnokite, sulphur, kornelite, montroseite, and ferricopiapite (Minrec 35.4.344).

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