Rruffite

rruffite

barahonaite-(Al)

mansfieldite

metazeunerite

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Formula: Ca2Cu(AsO4)2.2H2O
Hydrated arsenate, roselite group
Crystal System: Monoclinic
Specific gravity: 3.79 measured, 3.77 calculated
Hardness: 3
Streak: White
Colour: Pale blue, light blue
Luminescence: Not fluorescent under long wave or short wave UV
Solubility: Insoluble in water, acetone and hydrochloric acid
Environments

Volcanic igneous environments
Hydrothermal environments

Localities

At the type locality, the Maria Catalina mine, Pampa Larga mining district, Tierra Amarilla, Copiapó Province, Atacama, Chile, rruffite is a secondary mineral found in the oxidation zone of the copper - arsenic orebody. The vein in which rruffite was found is hosted in volcaniclastic rocks of Lower Cretaceous age (145 to 100.5 million years ago). This vein, which was mined for silver, ranges in thickness from 40 to 70 cm and can be traced for more than 300 metres on the surface. Primary mineralisation is found only in the lowest parts of the mine, and consists of pyrite, stibnite, native arsenic, quartz, baryte and ankeritesiderite. The oxidised portion of the vein largely consists of baryte and quartz with abundant mansfieldite. Silver is present as iodargyrite, chlorargyrite and native silver. Other arsenates found at the property include pharmacoalumite, arsenolite, barahonaite-(Al), betpakdalite, conichalcite, lavendulan, talmessite, philipsbornite and metazeunerite. Non-arsenate minerals include wulfenite, duftite and phosphohedyphane.
Rruffite, on the cotype samples, is found closely associated with quartz, baryte, mansfieldite, pharmacoalumite, conichalcite, metazeunerite and barahonaite-(Al). Rruffite crystals are in granular or blocky aggregates and druses, with single crystals up to 0.30 x 0.30 x 0.30 mm3 (CM 49.3.877-884).

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