Zincostrunzite

zincostrunzite

cacoxenite

plimerite

strunzite

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Formula: ZnFe3+2(PO4)2(OH)2.6.5H2O
Hydrated phosphate, strunzite group, zinc-bearing mineral
Crystal system: Triclinic
Specific gravity: 2.66 measured, 2.679 calculated for the ideal formula, 2.655 calculated for the empirical formula (Sitio do Castelo)
Hardness: 2½
Streak: White
Colour: Light brownish yellow (Sitio do Castelo), silvery white (Hagendorf-Süd)
Luminescence: Not fluorescent
Solubility: At room temperature, slowly soluble in dilute hydrochloric acid and rapidly soluble in concentrated hydrochloric acid
Environments

Pegmatites

Localities

There are two co-type localities, the Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany and the Sítio do Castelo Mine, Folgosinho, Gouveia, Guarda, Portugal.

At the the Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany, zincostrunzite occurs on the 67 metre level of the Cornelia mine opencut, where it was collected from a 30 to 40 50 cm nodule of former triphylite that had been replaced by vivianite, phosphophyllite and minor apatite. Zincostrunzite is found only in portions of crystals that otherwise fall in the composition range of strunzite (or ferristrunzite). These crystals occur as one of the youngest phases in a cavity mostly containing somewhat altered phosphophyllite crystals. Other secondary minerals found in the cavity include chalcophanite, strontium-bearing fluorapatite, hopeite (as epitactic overgrowths on phosphophyllite), jahnsite, zinc-bearing laueite, mitridatite, parahopeite, pseudolaueite, scholziteparascholzite, schoonerite, stewartite and whitmoreiteearlshannonite. Goethite and cryptomelane are also abundant in the oxidised zone.
The zincostrunzite makes up portions of needles that are up to about 5 mm long, forming bundles and divergent sprays (EJM 29.315-322).

The Sítio do Castelo Mine, Folgosinho, Gouveia, Guarda, Portugal, is well known for its diverse suites of unusual secondary phosphate minerals, which have formed as the result of intense weathering of primary triplitezwieselite, fluorapatite and isokite in association with sulphide minerals, such as sphalerite, arsenopyrite and chalcopyrite. Two types of secondary phosphate assemblages occur in the deposit.
The first type is derived from the alteration of triplitezwieselite yielding, in order of abundance, phosphosiderite, strengite, rockbridgeitefrondelite, cacoxenite, bermanite, beraunite, strunzite, stewartite, laueite, leucophosphite, benyacarite, fluorapatite, wavellite and kidwellite.
The second type is derived from the alteration of triplitezwieselite in association with fluorapatite and isokite yielding, in order of abundance, ludlamite, vivianite, strunzite, zinc-rich rockbridgeitefrondelite, manganese-rich phosphophyllite, hydroxylapatite, jahnsite-(CaMnFe), earlshannonite, lunokite and plimerite.
The zincostrunzite occurs in vugs in the second type of secondary phosphate assemblage on matrix composed of triplitezwieselite, fluorapatite and cryptomelane. Other minerals found in direct association with zincostrunzite are cacoxenite, plimerite, strengite and strunzite. Zincostrunzite has been found as crystals that are completely zincostrunzite as well as crystals that are mostly strunzite, but with zincostrunzite rims (EJM 29.315-322).
Zincostrunzite from the Sítio do Castelo Mine - Image

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