Arsentsumebite

arsentsumebite

bayldonite

brackebuschite

duftite

Images

Formula: Pb2Cu(AsO4)(SO4)(OH)
Compound arsenate, brackebuschite supergroup
Crystal System: Monoclinic
Specific gravity: 6.46 measured, 6.39 calculated
Hardness: 3½ (R&M 97.3.236-243)
Streak: Light green
Colour: Emerald-green, grass-green, apple-green, pale bluish green
Environments:

Hydrothermal environments

Arsentsumebite is a rare arsenate that occurs as aggregates of small, distorted crystals with individuals seldom exceeding 2 mm, or as powdery crusts.

Localities

At the Cap Garonne Mine, Le Pradet, Toulon, Var, Provence-Alpes-Côte d'Azur, France, the country rock consists of conglomerates and sandstones, and the minerals present are mainly secondary species derived from the breakdown of tetrahedrite/tennantite and galena.
Bariopharmacoalumite occurs as colourless to pale yellow interpenetrating cubes associated with mansfieldite, philipsbornite, beudantite, carminite, duftite, mimetite, scorodite, olivenite, arsentsumebite and lavendulan (AM 98.279).

At the Clara mine, Germany, arsentsumebite occurs in a hydrothermal polymetallic baryte-fluorite deposit (Webmin, HOM).

At the type locality, the Tsumeb mine, Oshikoto Region, Namibia, arsentsumebite occurs in the oxidised zone of a dolostone-hosted hydrothermal polymetallic ore deposit (Webmin, HOM, Mindat). It was not uncommon in the upper portion of the first oxidation zone, but considerably less common at greater depths, and apparently not present at all in the third oxidation zone.
The arsentsumebite occurs typically as crusts of small, distorted and closely intergrown crystals. In some attractive specimens it forms a contrasting colour backdrop to crystals of species such as blue-black azurite, cerussite or colourless to white anglesite. Much less conspicuously, arsentsumebite is often a constituent of the massive copper arsenate–rich matrix that is characteristic of many specimens; in such cases the arsentsumebite is intimately intergrown with species that include bayldonite, cerussite, conichalcite, duftite, gartrellite, malachite and smithsonite.
Arsentsumebite forms epimorphs after mimetite, encountered mainly in the first oxidation zone. Typically, these arsentsumebite pseudomorphs are microcrystalline and usually they have an earthy lustre; rarely they exhibit coarse crystallinity making for very attractive specimens. Much less common than the pseudomorphs after mimetite, arsentsumebite (sometimes in combination with bayldonite) was also found replacing azurite. Extensive coatings (or perhaps partial replacements) of arsentsumebite on cerussite have also been recorded.
In the deeper levels of the mine arsentsumebite inclusions in flattened anglesite crystals have been found. Also a second-oxidation-zone specimen exists featuring arsentsumebite encrusting blue (yes, blue!) wulfenite crystals on contrasting white anglesite. Arsentsumebite also occurs here with beudantite, though apparently only in the absence of carminite. A small second-oxidation-zone pocket comprised coarse chocolate-brown crystals of pseudo-hexagonal beudantite overgrowing framboidal aggregates of goethite on a matrix of partly oxidised sulphides. The beudantite is decorated with spherical tufts of duftite that are in turn supplanted by isolated crystals of spearmint-green arsentsumebite (R&M 97.3.236-243).

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