Formula: Mn2+Mn3+2O4
Multiple oxide, spinel subgroup, manganese-bearing mineral (Mindat).
Crystal System: Tetragonal
Specific gravity: 4.83 to 4.85 measured, 4.84 calculated
Hardness: 5½
Streak: Dark reddish brown, dark brown
Colour: Brown-black
Solubility: Soluble in hot hydrochloric acid with the evolution of Cl2.
Epitaxy: Hausmannite and jacobsite have been found as oriented intergrowths.
Common impurities: Zn,Fe,Ca,Ba,Mg

Metamorphic environments
Hydrothermal environments

Hausmannite is a primary mineral in hydrothermal veins. It may also be produced by metamorphism of manganiferous rocks.


At the Woods mine, New South Wales, Australia, hausmannite forms by oxidation and loss of SiO2 from neotocite and tephroite. (AJM 15.1&2.15)

At the Xianghualing Mine, Xianghualing Sn-polymetallic ore field, Linwu County, Chenzhou, Hunan, China, black hausmannite is found with with galena, pyrite, chalcopyrite and bornite (AESS).
Hausmannite from Xianghualing - Image

At the type locality, Oehrenstock, Langewiesen, Ilmenau, Ilm-Kreis, Thuringia, Germany, hausmannite occurs in a manganese ore deposit.
Hausmannite from Oehrenstock - Image

At Ilfeld, Harztor, Nordhausen, Thuringia, Germany, hausmannite pseudomorphs after manganite have been found with minor baryte (KL p147).
Hausmannite from Ilfeld - Image

At the Wyndham pit, Bigrigg, Egremont, Copeland, Cumbria, England, UK, hausmannite is associated with hematite (SY p162).


braunite to hausmannite, SiO2 and O2
3Mn2+Mn3+6O8(SiO4) ⇌ 7Mn2+Mn3+2O4 +3SiO2 + O2

braunite to hausmannite, rhodonite and O2
2Mn2+Mn3+6O8(SiO4) ⇌ 4Mn2+Mn3+2O4 + 2Mn2+SiO3 + O2
A higher temperature favours the forward reaction

braunite to tephroite, hausmannite and O2
3Mn2+Mn3+6O8(SiO4) ⇌ 3Mn2+2(SiO4) + 5Mn2+Mn3+2O4 + 2O2

hausmannite and O2 to bixbyite-(Mn)
4Mn2+Mn3+2O4 + O2 ⇌ 6Mn2O3

hausmannite and quartz to rhodonite and O2
2Mn2+Mn3+2O4 + 6SiO2 ⇌ 6Mn2+SiO3 + O2

hausmannite and rhodonite to tephroite and O2
2Mn2+Mn3+2O4 + 6Mn2+SiO3 ⇌ 6Mn2+2SiO4 + O2
A higher temperature favours the forward reaction (AM80.565)

manganosite and O2 to hausmannite
6MnO + O2 ⇌ 2Mn2+Mn3+2O4
A higher temperature favours the forward reaction

rhodochrosite and O2 to hausmannite and CO2
6MnCO3 + O2 ⇌ 2Mn2+Mn3+2O4 +6CO2
A higher temperature favours the forward reaction (AM80.571)

The diagram below is a Pourbaix diagram for manganese (GSJ). It shows the relationship between akhtenskite MnO2, bixbyite-(Mn) Mn2O3 and hausmannite Mn3O4.

Pourbaix manganese.jpg

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