Kumdykolite

kumdykolite

omphacite

phlogopite

niningerite

Images

Formula: Na(AlSi3O8)
Tectosilicate (framework silicate), feldspar group, orthorhombic paramorph of triclinic albite and of lingunite
Crystal System: Orthorhombic
Environments

Metamorphic environments
Meteorites

Kumdykolite is an orthorhombic high-pressure paramorph of albite. It may be a metastable phase formed at high temperatures followed by rapid cooling in the absence of water (Mindat).

Localities

At the Dabie Orogen, Eurasian Plate, Central China, kumdykolite formed during internal mineral carbonation within amphibole-hosted fluid inclusions in post-collisional hornblendite. Amphibole in the hornblendite trapped CO2-rich fluid inclusions at the magmatic stage, and mineral carbonation, referring to the reaction of minerals rich in divalent cations and CO2 into carbonate, occurred in situ within the fluid inclusions due to the interaction between trapped CO2-rich fluids and host amphibole during cooling of the hornblendite. Kumdykolite was produced along with calcite, dolomite, chlorite, talc, an SiO2 phase (quartz or cristobalite), a TiO2 phase (rutile or anatase), and mica during internal mineral carbonation within the fluid inclusions. It is estimated that kumdykolite in the fluid inclusions crystallised under near-surface conditions, which are significantly different from the conditions of crystallisation proposed in previous studies. It is further inferred that kumdykolite may crystallize metastably across the stability field of albite, and the presence of kumdykolite is not indicative of extreme thermobaric and fluid-absent conditions (AM 109.11.1995–2005).

At the České středohoří Mountains, Ústí nad Labem Region, Czech Republic, kumdykolite was discovered in an ultrahigh-pressure, diamond-bearing felsic garnet - kyanite - feldspar - quartz granulite from the northern Bohemian Massif. It is associated with phlogopite and quartz in a multiphase solid inclusion within garnet, considered to represent a trapped fluid or melt phase. Analysis revealed the presence of a sub-equant, elongated grain of kumdykolite reaching 20 μm in length.
The kumdykolite-bearing multiphase inclusion must have been trapped at a pressure greater than 4 GPa. The inclusion minerals, however, crystallised upon decompression and cooling during the exhumation (AM 99.1798–1801).

At the type locality, the Lake Kumdikol diamond deposit, Lake Kumdikol, Prirechnoye, Zerendy, Akmola Region, Kazakhstan, kumdykolite occurs in association with diopside, quartz-cristobalite, phengite-phlogopite, an unidentified aluminosilicate, calcic amphibole, dolomite, calcite or talc, as micrometer-scale mineral inclusions in omphacite of eclogite from the Kokchetav ultrahigh-pressure massif.
Kumdykolite is presumed to be a metastable phase formed at high temperatures followed by rapid cooling in the absence of water. It is further postulated that it may have resulted from the interaction between infiltrated melt and omphacite when the massif was exhumed from mantle depths to the base of the crust (EJM 21.1325-1334).
Kumdykolite from Lake Kumdikol - Image

At the Sahara 97072 meteorite, Sahara Desert, North Africa, kumdykolite occurs in the core of a concentrically zoned metal-sulphide nodule. It is proposed that kumdykolite formed above 1,027o and cooled rapidly enough to preserve its unique structure (AM 98.1070–1073).
Associated minerals include oldhamite, niningerite, zinc-rich daubréelite and sulphur-rich porous silica (HOM).

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