Löllingite

lollingite

skutterudite

safflorite

bismuth

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Formula: FeAs2
Oxidation states: Fe2+As1-2 (AM 87.1692-1698)
Arsenide, löllingite group
There is complete solid solution between safflorite and löllingite, limited solution of cobalt in rammelsbergite and no solid solution between löllingite and rammelsbergite (AM53.1856, Mindat).
Crystal System: Orthorhombic
Specific gravity: 7.43 measured, 7.472 calculated
Hardness: 5 to 5½
Streak: Greyish black
Colour: Steel grey to silver white
Common impurities: Bi
Environments:

Pegmatites
Metamorphic environments

Löllingite occurs in mesothermal deposits associated with other suphides and calcite gangue; it is also found in pegmatites (Webmin). Associated minerals include skutterudite, bismuth, nickeline, nickelskutterudite, siderite and calcite (HOM).

Localities

At the Emmons pegmatite, Greenwood, Oxford county, Maine, USA, löllingite forms masses to 15 cm across. Rare crude crystals occur in massive rhodochrosite. The Emmons pegmatite is an example of a highly evolved boron-lithium-cesium-tantalum enriched pegmatite (R&M 94.6.511).

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