Sengierite

sengierite

volborthite

vandenbrandeite

garnierite

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Formula: Cu2(UO2)2(VO4)2(OH)2.6H2O
Hydrated vanadate, uranyl mineral, carnotite group
Crystal System: Monoclinic
Specific gravity: 4.05 measured, 4.1 calculated
Hardness: 2½
Streak: Light green
Colour: Olive-green, yellowish green
Solubility: Soluble in acids
Very strongly RADIOACTIVE
Environments

Hydrothermal environments

Sengierite is an uncommon secondary mineral deposited from solutions derived from altering uraninite (Mindat).

Localities

At the type locality, the Luiswishi Mine, Kawama, Kipushi Territory, Haut-Katanga, DR Congo, an unusual radioactive mineral has been found in fissures cutting an argillaceous (clay-like) phase. This portion of the deposit consists essentially of chlorite and talc. Sengierite occurs as small, green, platy crystals that have a vitreous lustre and coat fracture surfaces in a flake-like fashion. The fissures containing the crystals occur along a fault and the siegenite is accompanied by black oxides containing iron, copper, cobalt and nickel and also some lustrous yellow volborthite. Less frequently it is found associated with vandenbrandeite, fibrous malachite, garnierite (a green nickel ore which has formed as a result of lateritic weathering of ultramafic rocks) and chrysocolla. Pitchblende is also found in small pockets along the fault where it has been partly altered to vandenbrandeite and kasolite. The sengierite is believed to be of supergene origin produced by deposition from solutions containing uranium, vanadium and copper derived from earlier minerals (AM 34.109-120).

At the Cole Mine, Bisbee, Cochise County, Arizona, USA, sengierite was discovered in a small pod of massive chalcocite in one of five sulphide-oxide veins; minor amounts of malachite were also found in this vein. The veins were in a very compact limestone, and the ore was a mixture of chalcocite, covellite and malachite, with pockets of chlorargyrite. Uranium mineralisation was present in the limestone as tyuyamunite which occurred as small yellow crystals lining cracks and fissures in the limestone adjacent to the massive chalcocite-covellite ore bodies.
Sengierite occurs in small pockets and patches up to 20 mm across, as quite minute rhombic-shaped platelets, the longer diagonals of which do not exceed 0.03 mm, but average less than 0.02 mm (AM 42.408–411).

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