Cabalzarite

cabalzarite

kutnohorite

tilasite

grischunite

Images

Formula: CaMg2(AsO4)2.2H2O
Valence: CaMg2(As5+O4)2.2H2O
Hydrated arsenate, tsumcorite group
Crystal System: Monoclinic
Specific gravity: 3.89 measured, 3.73 calculated
Hardness: 5
Streak: White
Colour: Light brownish to salmon-pink or orange-brown
Luminescence: Not fluorescent under UV
Common impurities: Mg may be replaced by minor Al and Fe3+
Environments

Sedimentary environments
Metamorphic environments

Localities

The type locality, Falotta, Tinizong, Surses, Albula Region, Grisons, Switzerland, belongs to the numerous manganese occurrences embedded in the radiolarites which overlay basalts in the Swiss Alps. The sedimentary ores recrystallised during the regional Alpine metamorphism under lowest greenschist facies conditions. The ore today consists mainly of braunite, rhodonite and spessartine. In addition, tinzenite, parsettensite, sursassite and strontium-bearing piemontite are locally abundant.
At Falotta, arsenic-bearing minerals occur in several types of veins. The types are:
(1) Massive brandtite/sarkinite veinlets with minor manganberzeliite and grischunite.
(2) Small open fractures containing free crystals of tilasite, kemmlitzite, bergslagite and geigerite, together with quartz and albite.
(3) Thin open fractures and quartz or carbonate veinlets, which occur in a very altered, cohesion-poor ore, and which host cabalzarite
Cabalzarite, like the other As-minerals of Falotta, results from the hydrothermal remobilisation of As during the retrogradation of the Alpine metamorphism.
Although the occurrence of cabalzarite is restricted to a 1 m2 outcrop in the Falotta mine, the mineral displays a broad range of morphologies:
(1) Isolated crystals up to 1 mm in size. The largest crystals look like axinite (hatchet-like), and their faces are often curved.
(2) Complex polycrystalline aggregates, up to 2 mm in length, located in vugs.
(3) Fibrous to tabular crystals up to 3 mm in length, forming radiating aggregates up to 5 mm across. These aggregates are developed in two dimensions within thin fractures, and formed spheroids where sufficient space was available.
(4) Aggregates of parallel needles filling veinlets up to 2 mm thick, associated with massive quartz, carbonate, and fibrous sursassite. Here, cabalzarite may be mistaken for sursassite.
In vugs, cabalzarite is associated with crystals of quartz, adularia, kutnohorite, tilasite, grischunite and arseniosiderite, with sprays of fine needles of tripuhyite and with black crusts of manganese oxy-hydroxides (ranciéite-takanelite). Arsenogoyazite is apparently a common but easily overlooked mineral associated with cabalzarite; it occurs as xenomorphic grains in cabalzarite, as white veinlets up to several millimeters in width, and as rare pseudo-rhombohedral crystals in vugs (AM 85.9.1307-1314).
Cabalzarite from Falotta - Image

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