Formula: Na2NaAlF6
Halide, perovskite group. Epitaxial mineral: thénardite (Mindat)
Specific gravity: 2.96 to 2.98
Hardness: 2½
Streak: White
Colour: Colourless, white, brown, grey, black; colourless in transmitted light.
Solubility: Soluble in sulphuric acid with evolution of HF. Slightly soluble in water. Readily soluble in AlCl3 solution (Mindat).
Melting Point: 1020°. Inverts to an isometric form at about 560° (Mindat).
Common impurities: Fe,Ca

Plutonic igneous environments
Volcanic igneous environments
Sedimentary environments rare

Cryolite is a late-stage mineral in some granite pegmatites; in tin-bearing granite; a vapour-phase mineral along fractures and in the groundmass of some fluorine-rich, topaz-bearing rhyolite; in pods in a carbonatite vein cutting biotite gneiss. Also as a rare authigenic (formed in place) component of the marl and shale of the Green River Formation (HOM). There are three principal fluoride minerals in igneous rocks, villiaumite, cryolite, and fluorite. Cryolite, is usually accompanied by quartz, and occurs in silica-rich but calcium-poor rocks, such as granite (AM55.126-134).
Common associates include chiolite, feldspar, fluorite, pachnolite, quartz and topaz (Mindat).
Cryolite, alters by weathering to a series of secondary fluorides, including pachnolite, thomsenolite, gearksutite, prosopite, cryolithionite, weberite and jarlite (Dana).

At Mont Saint-Hilaire, Quebec, Canada, cryolite, is associated with sodalite, villiaumite, eudialyte, lovozerite, natrolite, chabazite and aegirine (HOM).

At the Francon quarry, Montreal, Qebec, Canada, cryolite, is associated with calcite, dresserite, hydrodresserite, dawsonite and weloganite in the upper sill, and with siderite, calcite, gibbsite, quartz, doyleite and dawsonite in the lower sill. A unique assemblage in a very small zone of the lower sill contained cryolite, weloganite, elpidite, gibbsite, baryte, strontianite, calcite and marcasite. Perimorphs of gibbsite or fluorite mixed with doyleite after cryolite, have been found. (Minrec 37.1.24-26)

At the type locality, the Ivigtut cryolite, deposit, Greenland, Denmark, cryolite, occurs as a pegmatitic body in a granite stock intruded into gneiss, associated with zircon, wolframite (material between hübnerite and ferberite), weberite, topaz, thomsenolite, siderite, quartz, pyrite, prosopite, pachnolite, molybdenite, microcline, mica, jarlite, gearksutite, galena, fluorite, cryolithionite, columbite, chiolite, cassiterite and arsenopyrite (Mindat, HOM).


aegirine, albite and F2 to cryolite,, quartz, magnetite and O2
6NaFe3+Si2O6 + 3albite + 9F2 = 3Na2NaAlF6 + 21SiO2 + 2Fe2+Fe3+2O4 + 5O2

aegirine, anorthite, quartz and cryolite, to albite, fluorite, magnetite and O2
12NaFe3+Si2O6 + 9CaAl2Si2O8 + 21SiO2 + 3Na2NaAlF6 = 21NaAlSi3O8 + 9CaF2 + 4Fe2+Fe3+2O4 + O2
It is only in anorthite-poor siliceous rocks that cryolite, will form in preference to fluorite.

aegirine and cryolite, to villiaumite, magnetite, albite, quartz and O2
12NaFe3+Si2O6 + 3Na2NaAlF6 = 18NaF + 4Fe2+Fe3+2O4 + 3NaAlSi3O8 + 15SiO2 + O2
The forward reaction forming villiaumite occurs only in silica- and anorthite-poor rocks, such as phonolite.

albite, aegirine, F2 and CO2 to cryolite,, siderite, quartz and O2
NaAlSi3O8 + 2NaFe3+Si2O6 + 3F2 + 2CO2 = Na2NaAlF6 + 2FeCO3 + 7SiO2 +2O2
Large quantities of siderite occur with cryolite, at Ivigtut, Greenland, possibly formed by the above reaction.

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