Hellandite-(Y)

hellandite

hellandite-(Ce)

hellandite-(Y)

wakefieldite

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Formula: (Ca,REE)4Y2Al☐2(B4Si4O22)(OH)2
Nesosilicate (insular SiO4 groups), borosilicate, hellandite group, yttrium-bearing mineral
Crystal System: Monoclinic
Specific gravity: 2.95 to 3.63 measured, 3.5 calculated
Hardness: 4½ to 6½
Colour: Nut-brown, brownish red, black, grey, green, yellow, cream, pinkish
Environments

Pegmatites

Hellandite-(Y) occurs in granitic pegmatites associated with xenotime, wakefieldite, thorogummite, quartz, kainosite-(Y), fergusonite and chlorite group minerals (Mindat).

Localities

Hellandite was redefined as hellandite-(Y) by the IMA in 2000, so in the references cited below "hellandite" is assumed to refer to hellandite-(Y).
There are 5 co-type localities:
Mattagami Lake mine, Matagami, Nord-du-Québec, Québec, Canada
Evans-Lou Mine, Lac Saint-Pierre, Val-des-Monts, Les Collines-de-l'Outaouais RCM, Outaouais, Québec, Canada
Quyang pegmatite, Quyang County, Baoding, Hebei, China
Tawara, Hirukawa, Nakatsugawa City, Gifu Prefecture, Japan
Lindvikskollen Quarry, Lindvikskollen-Kalstadgangen pegmatite, Kragerø, Vestfold og Telemark, Norway

At the Evans-Lou mine, Lac Saint-Pierre, Val-des-Monts, Les Collines-de-l'Outaouais RCM, Outaouais, Quebec, Canada, the abandonned quarry exposes a pegmatite dyke that contains fergusonite, kainosite-(Y), tengerite-(Y), xenotime, wakefieldite and hellandite. The pegmatite cuts metamorphic rocks and is zoned with a quartz core, giant perthite-quartz zone, perthite-plagioclase-quartz zone and graphic granite (on the periphery). Rare earth minerals are mainly concentrated in the giant perthite-quartz zone.
Passing from the perthite-plagioclase-quartz zone into the giant perthite-quartz zone we progressively encounter the following assemblages:
apatite - fergusonite - titanite, titanite - fergusonite - allanite and titanite - allanite - spessartine. Near the quartz core there is a strong enrichment in boron, and hellandite appears along with fergusonite, some spessartine and rare allanite. All these phases are associated with quartz-rich portions of the pegmatite. Euxenite and tourmaline are also seen but not in association with hellandite.
Hellandite found on the dump commonly occurred in quartz, was spotted with chlorite, veined by red kainosite and stained white by tengerite-(Y). Less common alteration products were hematite, calcite, thorogummite, synchysite-(Y) and, perhaps, wakefieldite. In situ hellandite has been found abundantly in greyish quartz-rich portions of the giant perthite-quartz zone close to the barren white quartz core. Commonly hellandite, quartz and microcline are brecciated and cemented with a new generation of quartz. Fergusonite is a common associate of hellandite. Other primary minerals sometimes seen near hellandite include yttrium-bearing spessartine, allanite, uraninite, specularite, muscovite, pyrrhotite and chalcopyrite (CM 11.760-776).

At Predazzo, Trento Province, Trentino-Alto Adige, Italy, hellandite occurs in granite associated with a niobium oxide, allanite and various yttrium-bearing minerals (CM 11.760-776).

The Heftetjern pegmatite, Tørdal, Drangedal, Vestfold og Telemark, Norway, is a scandium-rich cleavelandite-amazonite granitic pegmatite. A striking feature of the Heftetjern pegmatite is the high level of scandium. Beryllium, yttrium, tin and tantalum are also characteristic elements. the Tørdal pegmatites are of mixed LCT (lithium, cesium, tantalum) and NYF (niobium, yttrium, fluorine) types.
Here, zinnwaldite and cassiterite are the most common lithium and tin minerals, respectively. The Heftetjern pegmatite is famous for its unique assemblage of scandium minerals such as kristiansenite, oftedalite and heftetjernite, as well as bazzite, scandiobabingtonite, cascandite and thortveitite (CM 53.345-356). A manganese-bearing hellandite-(Y) has been found as tiny pinkish yellow granular crystals in the pegmatite (Mindat).

At Lindvikskollen Quarry, Lindvikskollen-Kalstadgangen pegmatite, Kragerø, Vestfold og Telemark, Norway, hellandite is associated with a niobium oxide, allanite and various yttrium-bearing minerals (CM 11.760-776).

At Fabova hoľa, Pohronská Polhora, Brezno District, Banská Bystrica Region, Slovakia, two contrasting reaction coronae were developed around rare earth element accessory phosphates in metagranitic rocks.
Monazite-(Ce) breakdown resulted in impressive, though common, fluorapatite ± thorium-silicate + allanite-(Ce) + clinozoisite coronae. The alteration of xenotime-(Y) produced a novel type of secondary coronae consisting of a massive fluorapatite mantle zone and tiny satellite crystals of hellandite-(Y) and hingganite-(Y). The localised occurrence of yttriumboronberyllium silicates, which are associated closely with other secondary minerals, suggests the involvement of boron and beryllium during the metasomatic alteration of xenotime-(Y).
The granitic rocks underwent burial metamorphism under greenschist to lower amphibolite facies conditions. Subsequently, uplift and exhumation was accompanied by retrograde metamorphism; the activity of external fluids caused the formation of secondary coronae minerals around monazite-(Ce) and xenotime-(Y) (MM 86.4.586–605).

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