Aurostibite

aurostibite

gold

freibergite

jamesonite

Images

Formula: AuSb2
Antimonide, pyrite group, gold-bearing mineral
Crystal System: Isometric
Specific gravity: 9.98 measured, 9.91 calculated
Hardness: 3
Streak: Bronze
Colour: White
Environments


Hydrothermal environments

Aurostibite occurs in hydrothermal gold - quartz veins, in portions deficient in sulphur and containing other antimony minerals. Associated minerals include gold, freibergite, stibnite, jamesonite, chalcostibite, bournonite, boulangerite, arsenopyrite, pyrite, chalcopyrite, sphalerite, galena and tetrahedrite (HOM).

Localities

There are two co-type localities, the Giant Yellowknife mine, Yellowknife, North Slave Region, Northwest Territories, Canada, and the Chesterville Mine, McGarry Township, Timiskaming District, Ontario, Canada.

At the Giant Yellowknife mine, Yellowknife, North Slave Region, Northwest Territories, Canada, the type specimen is a two-inch fragment of greyish white impure vein quartz containing inclusions of chloritised and silicified wall-rock heavily mineralised with fine euhedral arsenopyrite. The walls of narrow vugs in the vein quartz are coated with minute imperfect rhombohedral crystals of dolomitic carbonate and thin flakes of sericite mica. Among the carbonate crystals in these vugs are scattered grains of hackly gold varying in size from about 20 microns up to 1 or 2 mm, accompanied by separate grains of aurostibite up to about 350 microns in size. Some of the gold grains appeared to be thinly coated with tarnished grey aurostibite.
The quartz contains irregular masses of bournonite, chalcopyrite, sphalerite, and bladed and fibrous masses of jamesonite and chalcostibite, associated with arsenopyrite and pyrite crystals. The wall-rock inclusions appear to be mineralised exclusively with disseminated euhedral crystals of pyrite and arsenopyrite. Single grains of gold and aurostibite occur scattered in quartz and carbonate immediately adjacent to fractures in the clear quartz. (AM 37.461-469).
The paragenesis of the Yellowknife ores is postulated as follows, oldest first:
1. A solution rich in sulphur, iron and arsenic was introduced, from which arsenopyrite and pyrite formed. Much of the arsenopyrite was formed before deposition of pyrite started.
2. A solution rich in sulphur, zinc, iron and copper, and containing minor tin was introduced. Sphalerite was the first mineral to be formed from this solution, followed by chalcopyrite, pyrrhotite and stannite.
3. There was, possibly, an early introduction of gold.
4. An antimony-rich solution was introduced, which also contained sulphur, gold, silver and lead, and possibly some copper and iron. Aurostibite and gold probably formed late in this period, with aurostibite forming shortly after the gold by reaction with excess antimony. Native lead and antimony were probably among the last minerals to form, and indicate an appreciable deficiency of sulphur during the later stages of mineralisation.
5. Late faulting and circulation of supergene or hypogene solutions, caused the formation of a second age of sulphides (AM 38.506-527).

At the Chesterville Mine, McGarry Township, Timiskaming District, Ontario, Canada, the aurostibite occurs sparsely as minute grains embedded in clear dark quartz near and attached to small hackly masses of bright yellow gold. Where gold is undisturbed below the surface of clear quartz, coatings of light grey aurostibite and darker grey freibergite partly occur on some of the extremities of the irregular gold grains.
A polished section reveals sparse grains of aurostibite up to 250 microns in diameter in clear quartz closely associated with gold, freibergite, chalcopyrite, jamesonite and galena. This clear quartz has largely absorbed and recrystallised an older, less transparent, milky-white quartz which is now mineralised with pyrite, arsenopyrite, gersdorffite, chalcopyrite, sphalerite and tetrahedrite (AM 37.461-469).

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