Descloizite

descloizite

vanadinite

pyromorphite

mottramite

Images

Formula: PbZn(VO4)(OH)
Anhydrous vanadate containing hydroxyl, adelite-descloizite group
Specific gravity: 6.2
Hardness: 3 to 3½
Streak: Orange to brownish-red
Colour: Brownish red, red-orange, reddish brown to blackish brown, nearly black
Solubility: Readily soluble in acids
Common impurities: Cu
Environments

Hydrothermal environments

Descloizite is a secondary mineral often found in the oxidation zones of metal ore deposits in association with mottramite in ore bodies containing vanadinite, pyromorphite, mimetite and cerussite. It has been found as pseudomorphs after vanadinite (Dana).

Localities

At the Nakhlak Mine, Anarak District, Nain County, Isfahan Province, Iran, epigenetic (formed later than the surrounding or underlying rock formation) vein deposits and metasomatic replacement bodies are hosted by a chalky Upper Cretaceous (100.5 to 66 million years ago) limestone. The limestone underwent dolomitisation prior to sulphide mineralisation. The principal primary ore mineral is galena, associated with minor or trace amounts of sphalerite, tetrahedrite -tennantite, pyrite and chalcopyrite as inclusions. The main secondary ore mineral is cerussite, sometimes associated with minor amounts of anglesite, plattnerite, wulfenite, minium, mimetite, covellite, chalcanthite, malachite and goethite. Many trace elements are present in the primary galena, but most notably it is rich in silver and antimony and poor in bismuth.
Dark green, drusy descloizite occurs with some specimens of red mimetite and orange wulfenite (Minrec 54.3.383-408).

Berg Aukas Mine, Namibia, is the world's best locality for crystallised specimens of descloizite; descloizite pseudomorphs after vanadinite and descloizite-coated vanadinite crystals have been found here.
Seven modes of occurrence of descloizite have been reported:
1. In minor amounts with massive first-formed willemite
2. With massive smithsonite as large well formed crystals in cavities
3. With calcite as infillings in large cavities and fissures where the surfaces were lined with vuggy descloizite and calcite
4. As narrow cross-cutting veinlets of descloizite with dolomite, in massive willemite
5. in isolation, with no associated secondary minerals
6. Fine grained, mixed with limonitic clay and calcite, dolomite, goethite-hematite, quartz and willemite
7. As black crystals in open cavities with massive goethite and minor hematite and pyrite (R&M 96.2.124-130)

At the Whitwell quarry, Derbyshire, England, UK, descloizite occurs on dolomite, associated with vanadinite (RES p137, 138)

At the Mammoth Mine, Arizona, USA, descloizite occurs with mottramite (Dana).

At the Kabwe mine, Central Province, Zambia, descloizite is an abundant mineral associated with tarbuttite or with smithsonite. It also occurs as thin lamellae in vanadinite (R&M 94.2.125).

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