Pseudojohannite

pseudojohannite

jachymovite

ktenasite

johannite

Images

Formula: Cu3(OH)2[(UO2)4O4(SO4)2].12H2O
or
Cu2+3(OH)2[(U6+O2)4O4(SO4)2].12H2O
Hydrated sulphate, uranyl mineral, zippeite group
Crystal System: Triclinic
Specific gravity: 4.31 measured, 4.38 calculated (we expect the measured value to be less than the calculated value since uranium, mass number 238, continuously alters to lead, mass number 207, by several stages of radioactive decay)
Colour: Moss-green
Luminescence: Green fluorescence under UV
RADIOACTIVE
Environments

Hydrothermal environments

Pseudojohannite is found in parageneses formed through the interaction of acidic sulphate mine drainage waters with uraninite or uranyl silicates (Mindat).

Localities

At the Musonoi Mine, Kolwezi, Mutshatsha, Lualaba, DR Congo, light green pseudojohannite appears in association with yellow uranopilite and orange-yellow metaschoepite on a saccharoidal quartz matrix containing many crosscutting veins of kasolite, uranophane and cuprosklodowskite. Other associated mineral species are relict selenium-bearing digenite, malachite, and a pale blue brochantite. The pseudojohannite crystals measure up to 25 μm in length, and are flattened along the cleavage plane. They coat several cm of tiny open veins.
The acid drainage waters probably result mainly from the oxidation of selenium-bearing digenite, and pseudojohannite subsequently forms through the reaction with oxidised uranium-bearing minerals such as kasolite, uranophane and cuprosklodowskite (AM 91.929-936).

Pseudojohannite from the Musonoi mine - Image

At the type locality, the Rovnost Mine, Jáchymov, Karlovy Vary District, Karlovy Vary Region, Czech Republic, to date (2006), only one sample is known to contain pseudojohannite. In this sample, pseudojohannite grows directly on strongly weathered uraninite containing pyrite, tennantite and chalcopyrite and is associated with johannite, uranopilite and gypsum. Pseudojohannite forms earthy moss-green, brittle aggregates up to 5 mm in size, or coatings with an uneven surface, which are composed of very fine crystals with sizes between 1 and 10 μm (AM 91.929-936).

Pseudojohannite from the Rovnost mine - Image

At the La Creusaz U-deposit near Les Marécottes village, canton Valais, Western Alps, Switzerland, pseudojohannite is directly associated with gypsum, johannite, ktenasite, marécottite and uranopilite in a broader paragenesis that also contains aluminium-bearing coconinoite, jáchymovite, jarosite, rabejacite, schröckingerite, zippeite, magnesiozippeite and zeunerite. These minerals encrust blocks of primary ore mainly consisting of uraninite and quartz. Pseudojohannite forms moss-green earthy aggregates up to 3 mm in size of poorly shaped crystals ~10 μm in length.
Since the end of the underground exploration in 1981, out-cropping veins and stockpiled uranium ore have been exposed to acid mine drainage water and atmospheric oxygen in the abandoned galleries. The oxidation of the sulphides (mainly pyrite and chalcopyrite) resulted in the production of acid, sulphate-rich waters. These waters reacted with uraninite, chamosite, calcite and siderite to form a rich assemblage of secondary uranyl minerals, including pseudojohannite (AM 91.929-936).

At the Widowmaker Mine, Fry Mesa, White Canyon Mining District, San Juan County, Utah, USA, pseudojohannite is associated with coal, uraninite and chalcocite (HOM).

Pseudojohannite from the Widowmaker mine - Image

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