Heflikite

heflikite

allanite-(Ce)

clinozoisite

scandium

Images

Formula: Ca2(Al2Sc)(Si2O7)(SiO4)O(OH)
Sorosilicate (Si2O7 groups), epidote group, epidote supergroup, scandium-bearing mineral
Crystal System: Monoclinic
Specific gravity: 3.537 calculated for the empirical formula
Hardness: 6
Streak: White
Environments

Pegmatites

Heflikite is a new mineral, approved in 2023 and to date (October 2024) reported only from the type localities

Localities

There are two co-type localities, the Heftetjern pegmatite, Tørdal, Drangedal, Telemark, Norway, and the Jordanów serpentinite quarry, Gmina Jordanów Śląski, Wrocław County, Lower Silesian Voivodeship, Poland.

The Heftetjern pegmatite, Tørdal, Drangedal, Telemark, Norway, is widely known for scandium mineralisation hosted in the granitic cleavelanditeamazonite pegmatite that has relatively high concentrations of tin, scandium, beryllium and lithium. The pegmatite is weakly zoned and consists dominantly of amazonite and albite with minor oligoclase, quartz, and a variety of micas. The main accessory minerals are beryl, spessartine, allanite-(Ce), uedaite-(Ce), gadolinite-(Y), cassiterite, scandium-rich ixiolite, zircon, monazite-(Ce), scandium-bearing pyrochlore supergroup minerals, milarite and phenakite.
A late-stage mineral assemblage, present mainly in vugs and fractures, comprises agakhanovite-(Y), bazzite, bertrandite, bohseite, cascandite, cerium - lanthanumscandium - enriched epidoteallanite minerals, yttrium-rich fluorite, heftetjernite, manganese-bearing hellandite-(Y), scandium-rich helvine, triclinic Ca-hingganite-(Y) (This lowering of symmetry to an acentric triclinic system is caused by different element occupancies on the gadolinite supergroup A-site (https://www.researchgate.net/figure/CHEMICAL-DATA-FOR-Ca-HINGGANITE-Y_tbl1_332933060)), scandium-rich garnet, oftedalite, rynersonite, scandiobabingtonite, thortveitite, triclinic titanite and an unnamed new species of OH-dominant analogue of gadolinite-(Y). Heflikite is a part of this late-stage mineral assemblage, and is associated with scandium-rich allanite-(Ce), rarely with allanite-(La) and hingganite-(Y). The epidote supergroup minerals from the locality form grey, green and brown, welldeveloped, transparent crystals and polycrystalline aggregates up to 10 mm in size (MM 88.228–243).

At the the Jordanów serpentinite quarry, Gmina Jordanów Śląski, Wrocław County, Lower Silesian Voivodeship, Poland, heflikite was discovered in a granitic pegmatite consisting mainly of quartz, sodic plagioclase and K-feldspar, with accessory pale green beryl, dark green dravite, and randomly scattered aggregates of greenish yellow clinochlore. Detailed investigations also revealed the presence of biotite, muscovite, spessartine, titanite, zircon, cassiterite, columbite-(Mn), fersmite, euxenite-(Y), monazite-(Ce), xenotime-(Y), allanite-(Ce), epidote, clinozoisite, rhabdophane-(La), rhabdophane-(Ce), rhabdophane-(Nd), pyrochlore group and microlite group minerals, phenakite, bavenite, bertrandite, milarite, tremolite, diopside, uraninite, aikinite, galena, scandium-rich ixiolite and a few scandium-bearing silicates, including cascandite, scandium-rich actinolite, scandio-winchite, kristiansenite, bazzite and heflikite.
At Jordanów Śląski, heflikite was found in the form of a few compositionally zoned euhedral to subhedral separate crystals and intergrowths with rare earth element-bearing clinozoisite and allanite-(Ce), reaching a maximum of 100 μm in size. Textural observations indicate that the crystallisation sequence starts with heflikite (core or inner zone of the aggregates), progresses to scandium-rich allanite-(Ce), scandium-rich clinozoisite and finally to clinozoisite (MM 88.228–243).

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